The　asymmetric　synthesis　of　multisubstituted　allylic　amino　acid　derivatives　was　accomplished　by　the　allylic　alkylation　of　a　chiral　glycine-based　nickel　complex　with　vinylethylene　carbonates.　High　enantioselectivities　and　diastereoselectivities　were　obtained　under　mild　reaction　conditions.　The　gram-scale　synthesis　was　carried　out　with　a　good　yield　and　high　enantioselectivity,　indicating　that　the　method　is　a　highly　efficient　route　to　chiral　multisubstituted　allylic　amino　acid　derivatives.