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author:

Liu, Ping (Liu, Ping.) [1] | Su, Han (Su, Han.) [2] | Liu, Yu (Liu, Yu.) [3] | Zhong, Yu (Zhong, Yu.) [4] | Xian, Chunxiang (Xian, Chunxiang.) [5] | Zhang, Yongqi (Zhang, Yongqi.) [6] | Wang, Xiuli (Wang, Xiuli.) [7] | Xia, Xinhui (Xia, Xinhui.) [8] | Tu, Jiangping (Tu, Jiangping.) [9]

Indexed by:

SCIE

Abstract:

Metallic lithium anode is considered as an ideal electrode for high-energy-density batteries. However, the uncontrollable growth of lithium dendrites, large volumetric change, and interfacial issues during the repeated plating and stripping processes severely hinder its practical applications. Herein, CoO nanosheets-decorated sponge nickel are synthesized as a host skeleton for thermal-injected Li (LCN). The conductive 3D matrix serves as a fast electron transfer path to decrease polarization and homogenize the local current density to suppress the Li dendrite. Moreover, the confined framework can relieve the volume change of lithium metal anodes. Furthermore, an artificial LiBr-LiF-rich solid-electrolyte interface (SEI) layer is constructed at the surface of LCN by the in situ spray-quenching method. Such an inorganic-rich SEI provides fast longitudinal Li+ transportation and facilitates the uniform deposition of lithium. Accordingly, the SEI@Li/CoO@SN (SLCN) symmetrical cells exhibit a steady overpotential within 35 mV for 1700 h at 1 mA cm(-2)/1 cm(-2) and achieve high Coulombic efficiency of 99.06% after 150 cycles. Matching with the sulfur cathode, the full cells present promoted rate performance and cycling stability and show a high initial capacity of 1274 mAh g(-1) and good capacity retention.

Keyword:

artificial solid-electrolyte interphases cobalt oxide nanosheets lithium metal anode sponge nickel spray quenching

Community:

  • [ 1 ] [Liu, Ping]Zhejiang Univ, Sch Mat Sci & Engn, State Key Lab Silicon Mat, Key Lab Adv Mat & Applicat Batteries Zhejiang Pro, Hangzhou 310027, Peoples R China
  • [ 2 ] [Su, Han]Zhejiang Univ, Sch Mat Sci & Engn, State Key Lab Silicon Mat, Key Lab Adv Mat & Applicat Batteries Zhejiang Pro, Hangzhou 310027, Peoples R China
  • [ 3 ] [Liu, Yu]Zhejiang Univ, Sch Mat Sci & Engn, State Key Lab Silicon Mat, Key Lab Adv Mat & Applicat Batteries Zhejiang Pro, Hangzhou 310027, Peoples R China
  • [ 4 ] [Zhong, Yu]Zhejiang Univ, Sch Mat Sci & Engn, State Key Lab Silicon Mat, Key Lab Adv Mat & Applicat Batteries Zhejiang Pro, Hangzhou 310027, Peoples R China
  • [ 5 ] [Xian, Chunxiang]Zhejiang Univ, Sch Mat Sci & Engn, State Key Lab Silicon Mat, Key Lab Adv Mat & Applicat Batteries Zhejiang Pro, Hangzhou 310027, Peoples R China
  • [ 6 ] [Wang, Xiuli]Zhejiang Univ, Sch Mat Sci & Engn, State Key Lab Silicon Mat, Key Lab Adv Mat & Applicat Batteries Zhejiang Pro, Hangzhou 310027, Peoples R China
  • [ 7 ] [Xia, Xinhui]Zhejiang Univ, Sch Mat Sci & Engn, State Key Lab Silicon Mat, Key Lab Adv Mat & Applicat Batteries Zhejiang Pro, Hangzhou 310027, Peoples R China
  • [ 8 ] [Tu, Jiangping]Zhejiang Univ, Sch Mat Sci & Engn, State Key Lab Silicon Mat, Key Lab Adv Mat & Applicat Batteries Zhejiang Pro, Hangzhou 310027, Peoples R China
  • [ 9 ] [Zhang, Yongqi]Univ Elect Sci & Technol China, Yangtze Delta Reg Inst Huzhou, Huzhou 313000, Peoples R China
  • [ 10 ] [Zhang, Yongqi]Univ Elect Sci & Technol China, Inst Fundamental & Frontier Sci, Huzhou 313000, Peoples R China
  • [ 11 ] [Xia, Xinhui]Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350116, Peoples R China

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ISSN: 2688-4062

Year: 2022

Issue: 6

Volume: 3

1 5 . 9

JCR@2022

1 3 . 9 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:91

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 33

SCOPUS Cited Count: 30

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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