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author:

Chen, Mingming (Chen, Mingming.) [1] | Zhang, Jiaxin (Zhang, Jiaxin.) [2] | Zhu, Xiajun (Zhu, Xiajun.) [3] | Liu, Zhihong (Liu, Zhihong.) [4] | Huang, Jianli (Huang, Jianli.) [5] | Jiang, Xianchai (Jiang, Xianchai.) [6] (Scholars:江献财) | Fu, Fengfu (Fu, Fengfu.) [7] (Scholars:付凤富) | Lin, Zhenyu (Lin, Zhenyu.) [8] (Scholars:林振宇) | Dong, Yongqiang (Dong, Yongqiang.) [9] (Scholars:董永强)

Indexed by:

Scopus SCIE

Abstract:

An ideal surface-enhanced Raman scattering (SERB) substrate should have high sensitivity, long-term stability, excellent repeatability, and strong antiinterference. In the present work, single-layer carbon-based dot (CD)-capped Ag nanoparticle aggregates (a-AgNPs/CDs) with high SERS activity are synthesized and hybridized with a hydrogel to prepare novel hydrogel SERS chips. Benefiting from the unique properties of a-AgNPs/CDs and the hydrogel, the constructed hydrogel SERS chips show excellent performances. Taking crystal violet detection as an example, the hydrogel SERS chips show a detection limit of around 1 x 10(-16) mol/L (high sensitivity), maintain above 96.40% of SERS activity even after 14 weeks of storage (long-term stability), and display point-to-point relative standard deviation (RSD) in one chip as low as 1.43% (outstanding repeatability) and RSD in different chips as low as 2.75% (excellent reproducibility). Furthermore, the self-extraction effect of the hydrogel enables the flexible hydrogel SERS chips to be used for analyzing various real samples including soybean milk, juices, and fruits without any complex pretreatment. For instance, the hydrogel SERS chips are able to detect trace thiram and 2-(4-thiazolyl)benzimidazole with the detection limits of 1 and 5 ppb in liquid samples, respectively, and of 1 and 2.5 ng/cm(2) on the peel of fruits, respectively. The self-extraction functional flexible SERS chips offer a reliable and convenient platform for the quick detection and on-site monitoring of chemical contaminants.

Keyword:

a-AgNPs/CDs flexible hydrogel pesticide residues surface-enhanced Raman scattering

Community:

  • [ 1 ] [Chen, Mingming]Fuzhou Univ, Coll Chem, MOE Key Lab Analyt Sci Food Safety & Biol, Fujian Prov Key Lab Anal & Detect Technol Food Sa, Fuzhou 350025, Peoples R China
  • [ 2 ] [Zhang, Jiaxin]Fuzhou Univ, Coll Chem, MOE Key Lab Analyt Sci Food Safety & Biol, Fujian Prov Key Lab Anal & Detect Technol Food Sa, Fuzhou 350025, Peoples R China
  • [ 3 ] [Zhu, Xiajun]Fuzhou Univ, Coll Chem, MOE Key Lab Analyt Sci Food Safety & Biol, Fujian Prov Key Lab Anal & Detect Technol Food Sa, Fuzhou 350025, Peoples R China
  • [ 4 ] [Liu, Zhihong]Fuzhou Univ, Coll Chem, MOE Key Lab Analyt Sci Food Safety & Biol, Fujian Prov Key Lab Anal & Detect Technol Food Sa, Fuzhou 350025, Peoples R China
  • [ 5 ] [Fu, Fengfu]Fuzhou Univ, Coll Chem, MOE Key Lab Analyt Sci Food Safety & Biol, Fujian Prov Key Lab Anal & Detect Technol Food Sa, Fuzhou 350025, Peoples R China
  • [ 6 ] [Lin, Zhenyu]Fuzhou Univ, Coll Chem, MOE Key Lab Analyt Sci Food Safety & Biol, Fujian Prov Key Lab Anal & Detect Technol Food Sa, Fuzhou 350025, Peoples R China
  • [ 7 ] [Dong, Yongqiang]Fuzhou Univ, Coll Chem, MOE Key Lab Analyt Sci Food Safety & Biol, Fujian Prov Key Lab Anal & Detect Technol Food Sa, Fuzhou 350025, Peoples R China
  • [ 8 ] [Huang, Jianli]Inst Grain & Oil Qual Supervis & Test Fujian, Fuzhou 350012, Peoples R China
  • [ 9 ] [Jiang, Xianchai]Fuzhou Univ, Coll Chem Engn, Fuzhou 350025, Peoples R China

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Source :

ACS APPLIED MATERIALS & INTERFACES

ISSN: 1944-8244

Year: 2022

Issue: 22

Volume: 14

Page: 26216-26224

9 . 5

JCR@2022

8 . 5 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:91

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 46

SCOPUS Cited Count: 50

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 5

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