With　increased　demand　for　various　chemical　raw　materials,　sudden　pollution　incidents　are　more　prone　to　occur　during　their　transportation　and　usage,　threatening　the　environment　and　human　health.　In　this　study,　discarded　tea　stalks　were　recycled　into　composite　materials　(FSC-X00:　X　represents　the　calcination　temperature)　by　impregnating　tea　stalks　in　Fe2+　solution　combined　with　subsequent　calcination.　X-ray　diffractometer　(XRD)　and　X-ray　photoelectron　spectroscopy　(XPS)　patterns　verified　the　existence　of　Fe-0　and　Fe2O3,　and　Fe2O3　was　gradually　reduced　to　Fe-0　when　the　calcination　temperature　was　raised　from　700　degrees　C　to　900　degrees　C.　FSC-X00　was　adopted　as　a　heterogeneous　catalyst　for　activating　H2O2　to　quickly　degrade　phenol　in　water　system.　The　degradation　experiments　indicated　that　FSC-600　exhibited　superior　degradation　performance　for　phenol　(20　mg/L)　within　5　min　and　80%　total　organic　carbon　(TOC)　removal　rate　at　pH　=　3　within　30　min.　The　effects　of　the　calcination　temperature,　the　pH　value　and　the　amount　of　H2O2　on　the　degradation　efficiency　were　investigated.　Competing　experiments　showed　that　fulvic　acid　(FA)　and　inorganic　salts　Na+　had　little　effect　on　the　degradation　performance.　The　FSC-600　catalyst　can　be　reused　by　thermal　reduction.　In　addition,　it　was　found　that　FSC-600　has　a　good　degradation　effect　on　ciprofloxacin　(CIP),　norfloxacin　(NOR)　and　enrofloxacin　(ENR),　indicating　that　FSC-600　catalysts　are　a　promising　candidate　for　quick　degradation　of　organic　pollutants　by　Fenton　reaction.　Electron　paramagnetic　resonance　(EPR)　spectra　analysis　indicated　that　center　dot　OH　is　the　dominant　reactive　oxygen　species　(ROS)　and　part　O-1(2)　from　O-2　also　participated　in　the　degradation.　This　study　provides　an　example　of　creating　catalysts　from　organic　solid　waste　for　use　in　emergency　treatment　for　phenol.