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author:

Lei, Yonggang (Lei, Yonggang.) [1] | Ng, Kim Hoong (Ng, Kim Hoong.) [2] | Zhang, Yingzhen (Zhang, Yingzhen.) [3] | Li, Zengxing (Li, Zengxing.) [4] | Xu, Shen (Xu, Shen.) [5] | Huang, Jianying (Huang, Jianying.) [6] | Lai, Yuekun (Lai, Yuekun.) [7]

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EI

Abstract:

In an attempt to construct efficient photocatalytic H2 production system, designing a practical way to integrate co-catalyst and semiconductor is of great importance for future commercialization. Herein, we report a facile one-pot loading of CdS onto WC through the facile solid–liquid mixing method. The resultant visible light-responsive WC-supported CdS photocatalyst, at different WC wt.%, is assessed in photocatalytic hydrogen production, with lactic acid as an electron donor. Experimental results confirmed the positive effects of WC, with 3 wt% WC-loaded CdS photocatalyst (CdS/WC) exhibiting the highest hydrogen evolution rate of 9180 μmol h−1 g−1. Such achievement is associated to 2.1 and 43 folds activity improvements from that of CdS/Pt(3 wt%) and pure CdS photocatalysts, respectively. Meanwhile, an apparent quantum efficiency (AQE) of 14.3% was also recorded by the same photocatalyst from the single-wavelength photocatalytic reaction at 420 nm. All these enhancements can be attributed to the incorporation of WC, which extending and improving the light absorbability of CdS. Concurrently, the adjoining WC also provides rapid electron transfer channel and water reduction site, which facilitate the spatial separation of charges while promoting the kinetics of hydrogen production reactions. This study presents a facile synthesis method for CdS/WC photocatalyst, which offers high reliability for industrial scale hydrogen production. © 2022 Elsevier B.V.

Keyword:

Cadmium sulfide CdS nanoparticles Hydrogen production II-VI semiconductors Lactic acid Light Photocatalytic activity Tungsten carbide

Community:

  • [ 1 ] [Lei, Yonggang]National Engineering Research Center of Chemical Fertilizer Catalyst (NERC-CFC), College of Chemical Engineering, Fuzhou University, Fuzhou; 350116, China
  • [ 2 ] [Lei, Yonggang]Qingyuan Innovation Laboratory, Quanzhou; 362801, China
  • [ 3 ] [Ng, Kim Hoong]Department of Chemical Engineering, Ming Chi University of Technology, New Taipei City, 24301, Taiwan
  • [ 4 ] [Ng, Kim Hoong]R&D Center of Biochemical Engineering Technology, Ming Chi University of Technology, New Taipei, Taiwan
  • [ 5 ] [Ng, Kim Hoong]Battery Research Center of Green Energy, Ming Chi University of Technology, New Taipei; 24301, Taiwan
  • [ 6 ] [Ng, Kim Hoong]Center for Environmental Sustainability and Human Health, Ming Chi University of Technology, New Taipei, 24301, Taiwan
  • [ 7 ] [Zhang, Yingzhen]National Engineering Research Center of Chemical Fertilizer Catalyst (NERC-CFC), College of Chemical Engineering, Fuzhou University, Fuzhou; 350116, China
  • [ 8 ] [Li, Zengxing]National Engineering Research Center of Chemical Fertilizer Catalyst (NERC-CFC), College of Chemical Engineering, Fuzhou University, Fuzhou; 350116, China
  • [ 9 ] [Xu, Shen]National Engineering Research Center of Chemical Fertilizer Catalyst (NERC-CFC), College of Chemical Engineering, Fuzhou University, Fuzhou; 350116, China
  • [ 10 ] [Huang, Jianying]National Engineering Research Center of Chemical Fertilizer Catalyst (NERC-CFC), College of Chemical Engineering, Fuzhou University, Fuzhou; 350116, China
  • [ 11 ] [Huang, Jianying]Qingyuan Innovation Laboratory, Quanzhou; 362801, China
  • [ 12 ] [Lai, Yuekun]National Engineering Research Center of Chemical Fertilizer Catalyst (NERC-CFC), College of Chemical Engineering, Fuzhou University, Fuzhou; 350116, China
  • [ 13 ] [Lai, Yuekun]Qingyuan Innovation Laboratory, Quanzhou; 362801, China

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Source :

Chemical Engineering Journal

ISSN: 1385-8947

Year: 2022

Volume: 434

1 5 . 1

JCR@2022

1 3 . 4 0 0

JCR@2023

ESI HC Threshold:66

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 25

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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