Coupling　photocatalytic　hydrogen　(H2)　evolution　with　selective　organic　synthesis　in　one　redox　cycle　showcases　great　potential　for　the　coinstantaneous　utilization　of　photoexcited　electrons　and　holes　toward　sustainable　production　of　value-added　fuels　and　chemicals.　Herein,　we　construct　one-dimensional/two-dimensional　(1D/2D)　WO3/ZnIn2S4　(WO3/ZIS)　hierarchical　Z-scheme　composites　for　bifunctional　integrated　light-driven　H2　production　and　biomass-derived　aromatic　alcohol　conversion.　The　superior　photoactivity　and　selectivity　over　WO3/ZIS　composites　compared　with　that　over　bare　WO3　nanorods　(NRs)　and　ZIS　nanosheets　(NSs)　can　be　attributed　to　the　assembly　of　the　Z-scheme　heterostructure.　The　construction　of　WO3/ZIS　direct　Z-scheme　composites　not　only　facilitates　the　charge　separation　dynamics　by　transporting　photoinduced　electrons　and　holes　to　spatially　separated　redox　sites　but　also　steers　the　selectivity　of　targeted　products　by　tuning　the　energy　band　potentials　to　endow　electrons　and　holes　with　stronger　reduction　and　oxidation　abilities.　The　mechanistic　studies　combining　the　control　experiments　and　electron　paramagnetic　resonance　spectroscopy　validate　the　free　radical　mechanism　of　the　benzyl　alcohol　photooxidation　reaction.　It　is　anticipated　that　this　work　would　offer　a　conducive　paradigm　for　the　ingenious　design　of　high-performance　Z-scheme　heterostructured　catalysts　toward　the　solar　light-driven　collaborative　redox　of　H2　production　and　selective　organic　synthesis.　©　Authors　2022