Construction　of　heterogeneous　nanostructures　for　electrode　materials　has　been　considered　as　an　efficient　approach　to　improve　the　associated　electrochemical　performance,　it　is　thus　crucial　to　rationally　design　favorable　heterostructures　and　engineer　the　interface　of　two　phases.　We　herein　report　the　elaborately　design　and　fabrication　of　heterostructured　nanohybrids　with　ZnS　and　carbon　coating　Cu2S　nanoplates　(Cu2S@ZnS/C).　Such　distinctive　nanostructures　develop　the　advance　heterostructures　with　carbon　decorating　can　remarkably　accelerate　electron　transfer　and　ionic　diffusion　kinetics　while　guarantee　the　structural　integrity　upon　sodium　ion　storage.　With　these　merits,　the　Cu2S@ZnS/C　nanohybrid　exhibits　outstanding　electrochemical　performance　with　a　high　reversible　capacity　of　352　mAh　g(-1)　at　10　A　g(-1)　and　long　cycle　stability　with　94.7%　capacity　retention　after　1000　cycles.　Electrochemical　kinetic　analysis　and　Density　functional　theory　(DFT)　calculations　demonstrate　the　decreased　ions　diffusion　energy　barrier　for　expediting　electrochemical　kinetics.　Of　note,　the　proof-of-concept　3D　printed　sodium　ion　batteries　have　been　set　up　by　coupling　the　3D　printed　Cu2S@ZnS/C　anode　with　3D　printed　Na3V2(PO4)(3)　cathode,　which　are　capable　of　delivering　high　and　stable　capacity　output.