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[期刊论文]

One-pot solvothermal preparation of graphene encapsulated SnO nanospheres composites for enhanced lithium storage

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author:

Zhang, Haohao (Zhang, Haohao.) [1] | Kong, Zhen (Kong, Zhen.) [2] | Gao, Xing (Gao, Xing.) [3] | Unfold

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EI

Abstract:

SnO based material is one of the most promising anode materials for lithium-ion batteries owing to its high theoretical capacity. However, the difficult synthesis process, large volume expansion and rapid capacity decay, etc., limited its further application. Herein, graphene encapsulated SnO nanospheres, self-assembled from numerous nano-sized secondary nanoparticles, have been successfully synthesized through an efficient one-pot solvothermal method within three hours. The graphene encapsulation and secondary particle assembly structure effectively improves the conductivity of SnO, shortens the ion transmission path and reduces its volume expansion during cycling, thus achieving cycle stability. SnO/G-3 H composite delivers a discharge capacity of 1307 mA h g−1 after 700 cycles at 800 mA g−1, and maintained an enhanced rate capability of 423 mA h g−1 at 3000 mA g−1. This simple, economic, and environmental-friendly synthesis route can be extended to the preparation of other transition metal oxide materials. © 2021 Elsevier B.V.

Keyword:

Anodes Encapsulation Graphene Ions Lithium-ion batteries Nanospheres Synthesis (chemical) Transition metal oxides Transition metals

Community:

  • [ 1 ] [Zhang, Haohao]School of Chemical and Biological Engineering, Qilu Institute of Technology, Jinan; 250200, China
  • [ 2 ] [Kong, Zhen]Institute of Materials for Energy and Environment, College of Materials Science and Engineering, Qingdao University, Qingdao; 266071, China
  • [ 3 ] [Gao, Xing]School of Chemical and Biological Engineering, Qilu Institute of Technology, Jinan; 250200, China
  • [ 4 ] [Zhang, Zhi]School of Chemical and Biological Engineering, Qilu Institute of Technology, Jinan; 250200, China
  • [ 5 ] [Fan, Jiaqi]School of Chemical and Biological Engineering, Qilu Institute of Technology, Jinan; 250200, China
  • [ 6 ] [Song, Jibin]MOE Key Laboratory for Analytical Science of Food Safety and Biology, College of Chemistry, Fuzhou University, Fuzhou; 350108, China
  • [ 7 ] [Li, Hongliang]Institute of Materials for Energy and Environment, College of Materials Science and Engineering, Qingdao University, Qingdao; 266071, China

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Source :

Colloids and Surfaces A: Physicochemical and Engineering Aspects

ISSN: 0927-7757

Year: 2021

Volume: 625

5 . 5 1 8

JCR@2021

4 . 9 0 0

JCR@2023

ESI HC Threshold:117

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count:

30 Days PV: 1

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