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Abstract:
For laser-induced fluorescence (LIF), the SNR and related concentration detectability was severely limited by background signal (noise). Herein, an axial-excitation LIF based on pinhole metal-capillary (PMC) and direct laser-diode excitation was proposed. An overall ~480 fold improvement on SNR was realized, because the laser-sidewall interaction (LSI) and related background signal (noise) can be effectively suppressed in PMC by avoidance of laser leakage and laser contact with capillary sidewall. For rhodamine B detection without sample enrichment, a detection limit of concentration (DLC) of 0.4 pM was obtained, which is 2.5 fold lower than the DLC (1 pM) of commercial LIFs equipped with bulky and expensive Ar+ laser. For selective detection of Cu2+, a DLC of 5 pM was realized, which is more than 40 fold lower than that of previous fluorimetry detection with similar quantum-dot probe. The PMC-LIF features compact (16 × 4 × 4 cm3), low-cost and high concentration detectability. © 2020
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Optics and Lasers in Engineering
ISSN: 0143-8166
Year: 2021
Volume: 139
5 . 6 6 6
JCR@2021
3 . 5 0 0
JCR@2023
ESI HC Threshold:105
JCR Journal Grade:1
CAS Journal Grade:2
Cited Count:
SCOPUS Cited Count: 2
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
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