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author:

Cai, Weicheng (Cai, Weicheng.) [1] | Huang, Hui (Huang, Hui.) [2] | Yang, Zhibo (Yang, Zhibo.) [3] | Shang, Ruichen (Shang, Ruichen.) [4] | Li, Xuejing (Li, Xuejing.) [5] | Ma, Chi (Ma, Chi.) [6] | Zhao, Jian (Zhao, Jian.) [7] | Liu, Pengbo (Liu, Pengbo.) [8] | Wang, Jian (Wang, Jian.) [9] | Wang, Wei (Wang, Wei.) [10]

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EI

Abstract:

For laser-induced fluorescence (LIF), the SNR and related concentration detectability was severely limited by background signal (noise). Herein, an axial-excitation LIF based on pinhole metal-capillary (PMC) and direct laser-diode excitation was proposed. An overall ~480 fold improvement on SNR was realized, because the laser-sidewall interaction (LSI) and related background signal (noise) can be effectively suppressed in PMC by avoidance of laser leakage and laser contact with capillary sidewall. For rhodamine B detection without sample enrichment, a detection limit of concentration (DLC) of 0.4 pM was obtained, which is 2.5 fold lower than the DLC (1 pM) of commercial LIFs equipped with bulky and expensive Ar+ laser. For selective detection of Cu2+, a DLC of 5 pM was realized, which is more than 40 fold lower than that of previous fluorimetry detection with similar quantum-dot probe. The PMC-LIF features compact (16 × 4 × 4 cm3), low-cost and high concentration detectability. © 2020

Keyword:

Argon lasers Costs Laser excitation Rhodamine B Semiconductor quantum dots Signal to noise ratio

Community:

  • [ 1 ] [Cai, Weicheng]Key Lab of Liaoning IC Technology, School of Biomedical Engineer, Faculty of Electronic Information and Electrical Engineering, Dalian University of Technology, Dalian; 116024, China
  • [ 2 ] [Huang, Hui]Key Lab of Liaoning IC Technology, School of Biomedical Engineer, Faculty of Electronic Information and Electrical Engineering, Dalian University of Technology, Dalian; 116024, China
  • [ 3 ] [Yang, Zhibo]Key Lab of Liaoning IC Technology, School of Biomedical Engineer, Faculty of Electronic Information and Electrical Engineering, Dalian University of Technology, Dalian; 116024, China
  • [ 4 ] [Shang, Ruichen]Key Lab of Liaoning IC Technology, School of Biomedical Engineer, Faculty of Electronic Information and Electrical Engineering, Dalian University of Technology, Dalian; 116024, China
  • [ 5 ] [Li, Xuejing]Key Lab of Liaoning IC Technology, School of Biomedical Engineer, Faculty of Electronic Information and Electrical Engineering, Dalian University of Technology, Dalian; 116024, China
  • [ 6 ] [Ma, Chi]Key Lab of Liaoning IC Technology, School of Biomedical Engineer, Faculty of Electronic Information and Electrical Engineering, Dalian University of Technology, Dalian; 116024, China
  • [ 7 ] [Zhao, Jian]School of Automotive Engineering, Dalian University of Technology, Dalian; 116024, China
  • [ 8 ] [Liu, Pengbo]School of Automotive Engineering, Dalian University of Technology, Dalian; 116024, China
  • [ 9 ] [Wang, Jian]Ministry of Education Key Laboratory of Analysis and Detection for Food Safety, Fuzhou University, Fuzhou; 350108, China
  • [ 10 ] [Wang, Wei]Ministry of Education Key Laboratory of Analysis and Detection for Food Safety, Fuzhou University, Fuzhou; 350108, China

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Source :

Optics and Lasers in Engineering

ISSN: 0143-8166

Year: 2021

Volume: 139

5 . 6 6 6

JCR@2021

3 . 5 0 0

JCR@2023

ESI HC Threshold:105

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 2

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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