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author:

Fang, Fei (Fang, Fei.) [1] | Gu, Jinglian (Gu, Jinglian.) [2] | You, Xinqiang (You, Xinqiang.) [3]

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Abstract:

An improved model for calculating physical properties and phase behavior of confined fluids (oil and gas resources in shale reservoirs) by considering adsorption film theory was developed based on the square-well chain-like fluid with variable well-width range (SWCF-VR) equation of state. The accuracy of the improved model is greatly increased via comparing the experimental data of argon in cylindrical pores at 87.3 K. The physical properties of pure component hydrocarbons, mixture hydrocarbons, and real Bakken oils in nanopores were predicted and analyzed. The results show that the properties of confined fluids are very different from those of bulk-phase fluids, where confinement decreases the gas-liquid phase equilibrium constant (K-value), bubble point pressure, and interfacial tension of the fluid. The presence of the adsorption film further decreases theK-value and bubble point and increases the capillary pressure, and these properties change more significantly in pore radius with only a few nanometers. The results demonstrate the importance of improving the accuracy in calculating the properties and phase behaviors of confined fluids and also draw the necessity of considering the adsorption film theory. © 2021 American Chemical Society

Keyword:

Adsorption Bottom hole pressure Energy resources Equations of state of gases Equilibrium constants Hydrocarbons Petroleum deposits Physical properties

Community:

  • [ 1 ] [Fang, Fei]Departement of Chemical Engineering, Laboratory of Chemical Process Intensification, College of Chemical Engineering, Fuzhou University, Fuzhou; Fujian; 350108, China
  • [ 2 ] [Gu, Jinglian]Departement of Chemical Engineering, Laboratory of Chemical Process Intensification, College of Chemical Engineering, Fuzhou University, Fuzhou; Fujian; 350108, China
  • [ 3 ] [You, Xinqiang]Departement of Chemical Engineering, Laboratory of Chemical Process Intensification, College of Chemical Engineering, Fuzhou University, Fuzhou; Fujian; 350108, China

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Source :

Industrial and Engineering Chemistry Research

ISSN: 0888-5885

Year: 2021

Issue: 35

Volume: 60

Page: 13094-13106

4 . 3 2 6

JCR@2021

3 . 8 0 0

JCR@2023

ESI HC Threshold:117

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 1

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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