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author:

Jia, Zhenzhen (Jia, Zhenzhen.) [1] | Hong, Ruoyu (Hong, Ruoyu.) [2]

Indexed by:

EI

Abstract:

The organic-inorganic hybrid coating was fabricated for anti-corrosion application using bisphenol A diglycidyl ether (BADGE) epoxy resin with inorganic silica nanoparticles prepared by sol-gel method. The precursor, tetraethyl orthosilicate (TEOS) formed via hydrolytic condensation the silica dispersed in the protective coating on the metal substrate that could prevent the permeation of corrosive media. In order to increase the functionality of the coating, the photocatalyst zinc oxide (ZnO) nanoparticles were added to bestow the light degradation on the coating. The as-fabricated nanoparticles and coatings were analyzed using Fourier Transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), scanning electron microscopy (SEM) and UV–vis spectrum (UV–vis) analysis. The anti-corrosion performance of the organic-inorganic hybrid coating was investigated by electrochemical impedance spectroscopy (EIS) and salt spray tests. Noteworthily, EIS results showed that the epoxy-silica organic-inorganic coating was109Ωcm2,which could increase the impedance modulus (at 0.01 Hz) of Q215 steel by about 7 orders of magnitude after immersion in 3.5 wt% NaCl aqueous solution for 96 h. The salt spray test results showed that metal substrate was still not completely corroded after 68 days. In addition, the addition of ZnO to the coating has photo-degradation effect on methyl orange and the photo-degradation efficiency can reach 55%. © 2021 Elsevier B.V.

Keyword:

Atmospheric corrosion Azo dyes Corrosion prevention Corrosion resistant coatings Degradation Electrochemical corrosion Electrochemical impedance spectroscopy Epoxy resins Fourier transform infrared spectroscopy II-VI semiconductors Inorganic coatings Metal nanoparticles Organic coatings organic-inorganic materials Photocatalytic activity Scanning electron microscopy Seawater corrosion Silica nanoparticles Sodium chloride Sol-gel process Sol-gels ZnO nanoparticles

Community:

  • [ 1 ] [Jia, Zhenzhen]College of Chemical Engineering, Fuzhou University, Fuzhou; 350108, China
  • [ 2 ] [Hong, Ruoyu]College of Chemical Engineering, Fuzhou University, Fuzhou; 350108, China

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Source :

Colloids and Surfaces A: Physicochemical and Engineering Aspects

ISSN: 0927-7757

Year: 2021

Volume: 622

5 . 5 1 8

JCR@2021

4 . 9 0 0

JCR@2023

ESI HC Threshold:117

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 21

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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