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author:

Du, Banghao (Du, Banghao.) [1] | Yu, Weiwei (Yu, Weiwei.) [2] | Yang, Lun (Yang, Lun.) [3] | Fan, Gongduan (Fan, Gongduan.) [4] (Scholars:范功端) | Yang, Shuo (Yang, Shuo.) [5] | Jiang, Hui (Jiang, Hui.) [6] | Bi, Shenglan (Bi, Shenglan.) [7] | Yu, Cheng (Yu, Cheng.) [8]

Indexed by:

SCIE

Abstract:

Steroid estrogens have received worldwide attention and given rise to great challenges of aquatic ecosystems security, posing potential adverse effects on aquatic organisms and human health even at low levels (ng/L). The present study focused on understanding the mobility and abiotic transformation of estrone (E1) and estrone-3-sulfate (E1-3S) over spatial and time scales during soil transport. Column transport experiments showed that the migration capacity of E1-3S was far stronger than E1 in soil. The calculated groundwater ubiquity score and leachability index values also indicated the high leaching mobility of E1-3S. The hydrolysis of E1-3S and abiotic transformation into estradiol and estriol was observed in the sterilized soil. Furthermore, possible transformation products (e.g., SE239, E2(378), E1 dimer(538), E1-E2 dimer(541)) of E1 and E1-3S in soil were analyzed and identified after the column transport experiments. The estrogenic activity was estimated by 17 beta-estradiol equivalency values during the transport process in aqueous and soil phases. Additionally, the potential leaching transport to groundwater of E1-3S requires further critical concern.

Keyword:

Abiotic transformation Estrone Estrone-3-sulfate Leaching Pollution risk

Community:

  • [ 1 ] [Du, Banghao]Chongqing Jiaotong Univ, Sch River & Ocean Engn, Key Lab Hydraul & Waterway Engn, Minist Educ, Chongqing 400074, Peoples R China
  • [ 2 ] [Yu, Weiwei]Chongqing Jiaotong Univ, Sch River & Ocean Engn, Key Lab Hydraul & Waterway Engn, Minist Educ, Chongqing 400074, Peoples R China
  • [ 3 ] [Yang, Lun]Chongqing Jiaotong Univ, Sch River & Ocean Engn, Key Lab Hydraul & Waterway Engn, Minist Educ, Chongqing 400074, Peoples R China
  • [ 4 ] [Yang, Shuo]Chongqing Jiaotong Univ, Sch River & Ocean Engn, Key Lab Hydraul & Waterway Engn, Minist Educ, Chongqing 400074, Peoples R China
  • [ 5 ] [Jiang, Hui]Chongqing Jiaotong Univ, Sch River & Ocean Engn, Key Lab Hydraul & Waterway Engn, Minist Educ, Chongqing 400074, Peoples R China
  • [ 6 ] [Yu, Cheng]Chongqing Jiaotong Univ, Sch River & Ocean Engn, Key Lab Hydraul & Waterway Engn, Minist Educ, Chongqing 400074, Peoples R China
  • [ 7 ] [Fan, Gongduan]Fuzhou Univ, Coll Civil Engn, Fuzhou 350116, Fujian, Peoples R China
  • [ 8 ] [Bi, Shenglan]Chongqing Comprehens Management Ctr Urban Pipelin, Chongqing 400014, Peoples R China

Reprint 's Address:

  • [Yu, Weiwei]Chongqing Jiaotong Univ, Sch River & Ocean Engn, Key Lab Hydraul & Waterway Engn, Minist Educ, Chongqing 400074, Peoples R China

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Source :

ENVIRONMENTAL GEOCHEMISTRY AND HEALTH

ISSN: 0269-4042

Year: 2021

Issue: 3

Volume: 44

Page: 911-924

4 . 8 9 8

JCR@2021

3 . 2 0 0

JCR@2023

ESI Discipline: ENVIRONMENT/ECOLOGY;

ESI HC Threshold:114

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 3

SCOPUS Cited Count: 4

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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