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Industrial sewage often contain metal ions and dyes, and it is difficult to efficiently remove them simultaneously. In this work, novel ternary MIL-53(Fe)/carbon quantum dots/noble metal (MIL-53(Fe)/CQDs/MNPs, MNPs = Ag, Pd, Au) nanocomposites have been rationally constructed and successfully fabricated by a facile two-step strategy with self-assembling and in-situ photoreduction. The resulting MIL-53(Fe)/CQDs/2%Au composite exhibits excellent photoactivity for the Cr(VI) reduction, the reduction ratio is nearly 100% after 20 min of visible light illumination. The rate constant of MIL-53(Fe)/CQDs/2%Au is calculated to be 0.1820 min(-1), which is around 7.4, 2.76, 1.77 and 1.47 times higher than that of as-prepared MIL-53(Fe), MIL-53(Fe)/CQDs, MIL-53 (Fe)/CQDs/2%Ag and MIL-53(Fe)/CQDs/2%Pd, respectively. More significantly, MIL-53(Fe)/CQDs/2%Au nanocomposite has been proven to serve as bifunctional photocatalyst for simultaneously removing Cr(VI)/dye mixed system pollutants. The superior photoactivity may be due to the enhanced light absorption intensity, the superior electrical conductivity of Au and CQDs, as well as surface plasmon resonance (SPR) effect of Au. In particular, the possible photocatalytic reaction mechanism has been carefully investigated and proposed.
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SEPARATION AND PURIFICATION TECHNOLOGY
ISSN: 1383-5866
Year: 2021
Volume: 255
9 . 1 3 6
JCR@2021
8 . 2 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
ESI HC Threshold:117
JCR Journal Grade:1
CAS Journal Grade:2
Cited Count:
WoS CC Cited Count: 65
SCOPUS Cited Count: 71
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 3