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author:

Zhou Jiang-Cong (Zhou Jiang-Cong.) [1] | Chen Meng-Ting (Chen Meng-Ting.) [2] | Lai Yi-Qing (Lai Yi-Qing.) [3] | Shi Chen (Shi Chen.) [4] | Wu De-Wu (Wu De-Wu.) [5] | Wu Quan-Sheng (Wu Quan-Sheng.) [6]

Indexed by:

SCIE PKU CSCD

Abstract:

In this study, a series of broadband emitting yellow phosphors Sr8MgAl(PO4)(7):xEu(2+) (SMAP:xEu(2+)) were synthesized by high temperature solid.state reaction; and the structure, luminescent properties and potential applica. tion in white light. emitting diode (WLED) were investigated. The X. ray diffraction (XRD) results showed that the SMAP:xE(u2)+ phosphors had monoclinic system and C2/m space group; and the activator Eu2+ ions can enter into the SMAP matrix and occupy the lattice site of Sr2+ ions. Diffuse reflectance spectroscopy showed that SMAP host was a wide band. gap material with a band gap of 3.60 eV. In addition, SMAP:xEu(2+) had a broad excitation range (280 similar to 500 nm), corresponding to the 4f(7)-> 4f(6)5d(1) transition of Eu2+ ions. Under the excitation of 380 nm near. ultraviolet light, there was an asymmetric yellow emission at the wavelength of 450 similar to 800 nm from multiple emission centers; and the emission peak was located at 590 nm. Based on Gaussian multi.peak fitting results, three emission centers were located at 528, 600 and 680 nm, respectively. Finally, the as. prepared yellow phosphor SMAP:0.05Eu(2+) and commercial blue phosphor BaMgAl10O17:Eu2+ were mixed and coated on the surface of 400 nm chip to fabricate WLED with good color temperature (3 344 K) and high color rendering index (90.1).

Keyword:

broadband emission high color rendering index near ultraviolet excitation Sr8MgAl(PO4)(7) white light-mitting diode yellow phosphor

Community:

  • [ 1 ] [Zhou Jiang-Cong]Longyan Univ, Coll Chem & Mat Sci, Longyan 364012, Fujian, Peoples R China
  • [ 2 ] [Wu De-Wu]Longyan Univ, Coll Chem & Mat Sci, Longyan 364012, Fujian, Peoples R China
  • [ 3 ] [Wu Quan-Sheng]Longyan Univ, Coll Chem & Mat Sci, Longyan 364012, Fujian, Peoples R China
  • [ 4 ] [Zhou Jiang-Cong]Fuzhou Univ, Coll Mat Sci, Fuzhou 350001, Peoples R China
  • [ 5 ] [Chen Meng-Ting]Fuzhou Univ, Coll Mat Sci, Fuzhou 350001, Peoples R China
  • [ 6 ] [Lai Yi-Qing]Fuzhou Univ, Coll Mat Sci, Fuzhou 350001, Peoples R China
  • [ 7 ] [Shi Chen]Fuzhou Univ, Coll Mat Sci, Fuzhou 350001, Peoples R China
  • [ 8 ] [Wu Quan-Sheng]Fuzhou Univ, Coll Mat Sci, Fuzhou 350001, Peoples R China

Reprint 's Address:

  • 周江聪

    [Zhou Jiang-Cong]Longyan Univ, Coll Chem & Mat Sci, Longyan 364012, Fujian, Peoples R China;;[Zhou Jiang-Cong]Fuzhou Univ, Coll Mat Sci, Fuzhou 350001, Peoples R China

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Source :

CHINESE JOURNAL OF INORGANIC CHEMISTRY

ISSN: 1001-4861

CN: 32-1185/O6

Year: 2021

Issue: 7

Volume: 37

Page: 1237-1244

0 . 8 2 7

JCR@2021

0 . 8 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:117

JCR Journal Grade:4

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 2

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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