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Abstract:
In this study, a series of broadband emitting yellow phosphors Sr8MgAl(PO4)(7):xEu(2+) (SMAP:xEu(2+)) were synthesized by high temperature solid.state reaction; and the structure, luminescent properties and potential applica. tion in white light. emitting diode (WLED) were investigated. The X. ray diffraction (XRD) results showed that the SMAP:xE(u2)+ phosphors had monoclinic system and C2/m space group; and the activator Eu2+ ions can enter into the SMAP matrix and occupy the lattice site of Sr2+ ions. Diffuse reflectance spectroscopy showed that SMAP host was a wide band. gap material with a band gap of 3.60 eV. In addition, SMAP:xEu(2+) had a broad excitation range (280 similar to 500 nm), corresponding to the 4f(7)-> 4f(6)5d(1) transition of Eu2+ ions. Under the excitation of 380 nm near. ultraviolet light, there was an asymmetric yellow emission at the wavelength of 450 similar to 800 nm from multiple emission centers; and the emission peak was located at 590 nm. Based on Gaussian multi.peak fitting results, three emission centers were located at 528, 600 and 680 nm, respectively. Finally, the as. prepared yellow phosphor SMAP:0.05Eu(2+) and commercial blue phosphor BaMgAl10O17:Eu2+ were mixed and coated on the surface of 400 nm chip to fabricate WLED with good color temperature (3 344 K) and high color rendering index (90.1).
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CHINESE JOURNAL OF INORGANIC CHEMISTRY
ISSN: 1001-4861
CN: 32-1185/O6
Year: 2021
Issue: 7
Volume: 37
Page: 1237-1244
0 . 8 2 7
JCR@2021
0 . 8 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
ESI HC Threshold:117
JCR Journal Grade:4
CAS Journal Grade:4
Cited Count:
WoS CC Cited Count: 2
SCOPUS Cited Count:
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
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