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Mostly, surface-enhanced Raman scattering (SERS) sensors used the Raman characteristic bands concentrated in the Raman "fingerprint" region (500-1800 cm(-1)), which may result in spectral overlapping interference. The study of the response in the Raman-silent region (10-500 and 1800-2800 cm(-1)) can help overcome this problem. Hydrogen sulfide (H2S) gas causes a great threat to human's health, but its low concentration in the airborne species is a challenge for sensitive and selective detection. Herein, a novel low-wavenumber (10-500 cm(-1)) SERS sensor for H2S gas detection has been developed based on gold nano-bipyramids (Au NBPs) encapsulated by zeolitic imidazolate framework-8 (ZIF-8) (Au NBPs@ZIF-8). The sensor takes advantage of the high adsorption capacity of ZIF-8 toward H2S gas and the H2S-triggered SERS spectral changes in the low-wavenumber Raman-silent region. A clear SERS peak of Au-Br at similar to 175 cm(-1) generated from Au NBPs@ZIF-8 showed a decrease in the presence of H2S because of the competition of adsorption sites between Au-S and Au-Br bonds. Furthermore, Au NBPs@ZIF-8 can enrich and monitor the level of H2S gas with high efficiency and low interference. The developed sensor has a detection range of 0.2 nM to 20 mM with a limit of detection (LOD) of 0.17 nM. The developed sensor had been applied to detect the H2S gas released from the spoiled fish meat with high selectivity.
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ACS SENSORS
ISSN: 2379-3694
Year: 2020
Issue: 12
Volume: 5
Page: 3964-3970
7 . 7 1 1
JCR@2020
8 . 3 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
ESI HC Threshold:160
JCR Journal Grade:1
CAS Journal Grade:1
Cited Count:
SCOPUS Cited Count:
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
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