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author:

Chen, Jiaming (Chen, Jiaming.) [1] | Guo, Longhua (Guo, Longhua.) [2] | Chen, Lifen (Chen, Lifen.) [3] | Qiu, Bin (Qiu, Bin.) [4] (Scholars:邱彬) | Hong, Guolin (Hong, Guolin.) [5] | Lin, Zhenyu (Lin, Zhenyu.) [6] (Scholars:林振宇)

Indexed by:

SCIE

Abstract:

Mostly, surface-enhanced Raman scattering (SERS) sensors used the Raman characteristic bands concentrated in the Raman "fingerprint" region (500-1800 cm(-1)), which may result in spectral overlapping interference. The study of the response in the Raman-silent region (10-500 and 1800-2800 cm(-1)) can help overcome this problem. Hydrogen sulfide (H2S) gas causes a great threat to human's health, but its low concentration in the airborne species is a challenge for sensitive and selective detection. Herein, a novel low-wavenumber (10-500 cm(-1)) SERS sensor for H2S gas detection has been developed based on gold nano-bipyramids (Au NBPs) encapsulated by zeolitic imidazolate framework-8 (ZIF-8) (Au NBPs@ZIF-8). The sensor takes advantage of the high adsorption capacity of ZIF-8 toward H2S gas and the H2S-triggered SERS spectral changes in the low-wavenumber Raman-silent region. A clear SERS peak of Au-Br at similar to 175 cm(-1) generated from Au NBPs@ZIF-8 showed a decrease in the presence of H2S because of the competition of adsorption sites between Au-S and Au-Br bonds. Furthermore, Au NBPs@ZIF-8 can enrich and monitor the level of H2S gas with high efficiency and low interference. The developed sensor has a detection range of 0.2 nM to 20 mM with a limit of detection (LOD) of 0.17 nM. The developed sensor had been applied to detect the H2S gas released from the spoiled fish meat with high selectivity.

Keyword:

hydrogen sulfide low-wavenumber Raman-silent region SERS sensor ZIF-8

Community:

  • [ 1 ] [Chen, Jiaming]Xiamen Univ, Dept Lab Med, Xiamen Key Lab Genet Testing, Affiliated Hosp 1, Xiamen 361005, Fujian, Peoples R China
  • [ 2 ] [Hong, Guolin]Xiamen Univ, Dept Lab Med, Xiamen Key Lab Genet Testing, Affiliated Hosp 1, Xiamen 361005, Fujian, Peoples R China
  • [ 3 ] [Chen, Jiaming]Fuzhou Univ, Coll Chem, MOE Key Lab Analyt Sci Food Safety & Biol, Fujian Prov Key Lab Anal & Detect Technol Food Sa, Xiamen 350116, Fujian, Peoples R China
  • [ 4 ] [Qiu, Bin]Fuzhou Univ, Coll Chem, MOE Key Lab Analyt Sci Food Safety & Biol, Fujian Prov Key Lab Anal & Detect Technol Food Sa, Xiamen 350116, Fujian, Peoples R China
  • [ 5 ] [Lin, Zhenyu]Fuzhou Univ, Coll Chem, MOE Key Lab Analyt Sci Food Safety & Biol, Fujian Prov Key Lab Anal & Detect Technol Food Sa, Xiamen 350116, Fujian, Peoples R China
  • [ 6 ] [Guo, Longhua]Jiaxing Univ, Coll Biol Chem Sci & Engn, Jiaxing 314001, Zhejiang, Peoples R China
  • [ 7 ] [Chen, Lifen]Jiaxing Univ, Coll Biol Chem Sci & Engn, Jiaxing 314001, Zhejiang, Peoples R China

Reprint 's Address:

  • 郭隆华 林振宇

    [Hong, Guolin]Xiamen Univ, Dept Lab Med, Xiamen Key Lab Genet Testing, Affiliated Hosp 1, Xiamen 361005, Fujian, Peoples R China;;[Lin, Zhenyu]Fuzhou Univ, Coll Chem, MOE Key Lab Analyt Sci Food Safety & Biol, Fujian Prov Key Lab Anal & Detect Technol Food Sa, Xiamen 350116, Fujian, Peoples R China;;[Guo, Longhua]Jiaxing Univ, Coll Biol Chem Sci & Engn, Jiaxing 314001, Zhejiang, Peoples R China

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Source :

ACS SENSORS

ISSN: 2379-3694

Year: 2020

Issue: 12

Volume: 5

Page: 3964-3970

7 . 7 1 1

JCR@2020

8 . 3 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:160

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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