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author:

Yu, Xiaochen (Yu, Xiaochen.) [1] | Zheng, Jia (Zheng, Jia.) [2] | Zhou, Zhaoxi (Zhou, Zhaoxi.) [3] | Chen, Qihui (Chen, Qihui.) [4] | Hong, Maochun (Hong, Maochun.) [5] | Fu, Heqing (Fu, Heqing.) [6]

Indexed by:

EI SCIE

Abstract:

Firstly, cerium dioxide(CeO2) was modified by 3-(Methylacryloxyl)propyltrimethoxy silane (KH-570), and modified CeO2 (mCeO(2)) was prepared. Then poly (urethane-acrylate) was modified by mCeO(2), and poly (urethane-acrylate)/modified CeO2 (PUA/mCeO(2)) composites with ultraviolet absorption property were prepared. The morphology, thermal hydrophobicity, mechanical properties, optical properties, and UV-absorption properties of PUA/mCeO(2) composites were studied. XRD and SEM analysis showed that the modified CeO2 had better dispersion in the matrix than that of pure CeO2. Ultraviolet-visible spectrum and thermogravimetric analysis were used to characterize the optical properties and thermal stability of PUA/mCeO(2) composites. The results showed that with the increasing of the mCeO(2) content, the UV-absorption property of PUA/mCeO(2) composites was improved gradually. When the content of mCeO(2) is 3%, the absorption of ultraviolet of PUA/mCeO2 composites is about 5 times of pure PUA film, and the absorption band is mainly in the UVA section. The thermal stability of PUA/mCeO(2) composites was improved with the adding of mCeO(2). With the increasing of mCeO(2) content, the contact angle of PUA/mCeO(2) composites increased significantly. And the UV-absorption mechanism of PUA/mCeO(2) Composites was studied. UV-curable PUA/mCeO(2) composites have good UV absorption property and water resistance. They will be used in the sun screen and protect people's skin.

Keyword:

composites copolymers functionalization of polymers polyurethane resins

Community:

  • [ 1 ] [Yu, Xiaochen]Fuzhou Univ, Coll Chem, Fuzhou, Peoples R China
  • [ 2 ] [Zheng, Jia]Fuzhou Univ, Coll Chem, Fuzhou, Peoples R China
  • [ 3 ] [Yu, Xiaochen]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou, Peoples R China
  • [ 4 ] [Zheng, Jia]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou, Peoples R China
  • [ 5 ] [Chen, Qihui]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou, Peoples R China
  • [ 6 ] [Hong, Maochun]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou, Peoples R China
  • [ 7 ] [Fu, Heqing]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou, Peoples R China
  • [ 8 ] [Zhou, Zhaoxi]South China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510640, Peoples R China
  • [ 9 ] [Fu, Heqing]South China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510640, Peoples R China

Reprint 's Address:

  • [Fu, Heqing]South China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510640, Peoples R China

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Source :

JOURNAL OF APPLIED POLYMER SCIENCE

ISSN: 0021-8995

Year: 2021

Issue: 31

Volume: 138

3 . 0 5 7

JCR@2021

2 . 7 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:117

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 2

SCOPUS Cited Count: 2

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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