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Firstly, cerium dioxide(CeO2) was modified by 3-(Methylacryloxyl)propyltrimethoxy silane (KH-570), and modified CeO2 (mCeO(2)) was prepared. Then poly (urethane-acrylate) was modified by mCeO(2), and poly (urethane-acrylate)/modified CeO2 (PUA/mCeO(2)) composites with ultraviolet absorption property were prepared. The morphology, thermal hydrophobicity, mechanical properties, optical properties, and UV-absorption properties of PUA/mCeO(2) composites were studied. XRD and SEM analysis showed that the modified CeO2 had better dispersion in the matrix than that of pure CeO2. Ultraviolet-visible spectrum and thermogravimetric analysis were used to characterize the optical properties and thermal stability of PUA/mCeO(2) composites. The results showed that with the increasing of the mCeO(2) content, the UV-absorption property of PUA/mCeO(2) composites was improved gradually. When the content of mCeO(2) is 3%, the absorption of ultraviolet of PUA/mCeO2 composites is about 5 times of pure PUA film, and the absorption band is mainly in the UVA section. The thermal stability of PUA/mCeO(2) composites was improved with the adding of mCeO(2). With the increasing of mCeO(2) content, the contact angle of PUA/mCeO(2) composites increased significantly. And the UV-absorption mechanism of PUA/mCeO(2) Composites was studied. UV-curable PUA/mCeO(2) composites have good UV absorption property and water resistance. They will be used in the sun screen and protect people's skin.
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JOURNAL OF APPLIED POLYMER SCIENCE
ISSN: 0021-8995
Year: 2021
Issue: 31
Volume: 138
3 . 0 5 7
JCR@2021
2 . 7 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
ESI HC Threshold:117
JCR Journal Grade:2
CAS Journal Grade:3
Cited Count:
WoS CC Cited Count: 2
SCOPUS Cited Count: 2
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 2
Affiliated Colleges: