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author:

尹华 (尹华.) [1] | 林韵 (林韵.) [2] | 黄清明 (黄清明.) [3]

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CQVIP PKU CSCD

Abstract:

合成了以糠醛水杨酰腙为配体的一个镍配合物Ni(C12H9N2O3)2(C5H5N)2,进行红外光谱和紫外光谱分析,并测定晶体结构,该晶体为深红褐色,属三斜晶系,空间群为Pi,晶胞参数:α=1.02003(4)m,b=1.11947(6)nm,c=1.48619(9)nm,α=105.960(2)°,β=93.819(2)°,γ=100.457(1)°.晶体结构分析表明,Ni^2+具有畸变的八面体配位构型,配位原子分别来自两个二齿配体糠醛水杨酰腙的两个氧原子和两个氮原子以及两个配位吡啶的氮原子。

Keyword:

晶体结构 水杨酰肼 镍配合物

Community:

  • [ 1 ] 福州大学测试中心,福建福州350002

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Source :

福州大学学报:自然科学版

ISSN: 1000-2243

CN: 35-1337/N

Year: 2004

Issue: 3

Volume: 32

Page: 358-361

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count: -1

30 Days PV: 3

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