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author:

郑玉婴 (郑玉婴.) [1] | 吴文士 (吴文士.) [2]

Indexed by:

CQVIP CSCD

Abstract:

在甲醇和DMF溶剂里,以Schiff碱水杨醛缩氨基硫脲(简写为HL)和六水二氯化钴合成了配合物[CoHL2]·H2O·DMF.在配合物[CoHL2]中,钴(Ⅱ)原子具有扭曲的N2O2S2八面体配位构型,晶体通过分子间氢键作用形成二维的无限网状结构.红外光谱表明,配体在形成配合物后,vs=0,vc=0和vc=N红移.荧光光谱表明,配合物金属对配体规n-π^*激发引起的荧光发射峰有较大的影响.

Keyword:

晶体结构 水杨醛缩氨基硫脲 荧光性质 钴配合物

Community:

  • [ 1 ] 福州大学化学化工学院,福建福州350002
  • [ 2 ] 华侨大学材料学院,福建泉州362021

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Source :

分子科学学报

ISSN: 1000-9035

Year: 2006

Issue: 1

Volume: 22

Page: 41-46

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count: -1

30 Days PV: 1

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