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Abstract:
含μ-Cl桥的三核钼簇阴离子[Mo_3(μ_3-O)(μ-Cl)_3(μ-OAc)_3Cl_3]-在Fe~(3+)作用下发生簇解反应,形成钼同多酸盐[FeCl(DMF)_5][Mo_6O_(19)](1)。在合成[Mo_3(μ-S_2)(μ-S_2)_3(dtp)_3Cl]簇合物的反应中如果有CaI存在,则形成钼磷杂多酸盐(Et_4N)_4[PMo_(12)O_(40)](DMF)_2(2)。本文报道这两个多钼酸盐化合物的晶体结构,并讨论有关的簇解反应。
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化学学报
ISSN: 0567-7351
CN: 31-1320/O6
Year: 1992
Issue: 04
Page: 348-356
1 . 7 0 0
JCR@2023
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30 Days PV: 1
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