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采用水热合成法合成了一种结构新颖的多硼钒氧簇化合物(H2dap)6H[V12B16O54(OH)4]·12H2O(dap=1,2-diaminopropane),对化合物1进行了单晶X射线衍射,结果表明化合物1属于单斜晶系,C2/c空间群,晶胞参数a=19.027(4),b=16.142(3),c=26.679(5),α=90°,β=101.06(3)°,γ=90°,V=8 042(3)nm3,Z=4,Dc=1.962g·cm-3,μ=1.456mm-1,F(000)=4 776,7 635个可观察独立衍射点射点[I>2σ(I)],最后结构精修到偏离因子R1=0.0626,wR2=0.192 ...
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光谱学与光谱分析
ISSN: 1000-0593
CN: 11-2200/O4
Year: 2015
Issue: 09
Volume: 35
Page: 2625-2628
0 . 2 7 5
JCR@2015
0 . 7 0 0
JCR@2023
JCR Journal Grade:4
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 4
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