Abstract:
通过溶液挥发法用咪唑溴鎓盐为模板剂与碘化铅反应,合成了有机-无机杂化聚合物1{[(C4H6N2)2C2H4]2Pb3I10}n.通过X-射线单晶衍射测定了其晶体结构,并进行了红外、紫外、元素分析等表征.结构解析表明:该化合物属于三斜晶系,P-1空间群,a=10.4184(17),b=10.959(2),c=12.2760(19),α=113.051(5)°,β=95.050(2)°,γ=115.161(3)°,V=1111.5(3)3,Z=1.该化合物由是由有机阳离子[(C4H6N2)2C2H4]2+和无机聚阴离子链[Pb3I10]n4n-组成的1-D链结构,有机组分与无机组分之间通过...
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宁德师范学院学报(自然科学版)
Year: 2017
Issue: 04
Volume: 29
Page: 351-355
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 1
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