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Abstract:
The influences of temperature, pressure, catalyst content, H2O2 content and mol ratio of propylene to H2O2 on epoxidation of propylene with H2O2 over TS-1 in a small-scale three phase loop thermosphonic reactor were investigated. The proper reaction condition was determined as follows: mol ratio of propylene to H2O2 was 1.1—1.3, temperature was 30—45?℃, reaction temperature rise was below 15?℃, pressure was 0—0.1?MPa, catalyst content was 3%—6%,and H2O2 content was 3%—5%.The conversion of H2O2 is above 94%,and selectivity of propylene is up to 96%. At these conditions, the yield of PO is higher than a figure of about 80%,which is achieved using conventional reactor. This reactor can realize catalyst regeneration continuously. This viable reactor can also be applied in other oxidation processes using TS-1, i.e. hydroxylation of phenol, ammoxidation of cyclohexanone.The results will lay a foundation for the development of the reactor in propylene epoxidation process.
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化工学报
ISSN: 0438-1157
CN: 11-1946/TQ
Year: 2001
Issue: 1
Volume: 52
Page: 84-87
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 1
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