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author:

陈晓晖 (陈晓晖.) [1] | 李世军 (李世军.) [2] | 陈宪 (陈宪.) [3] | 米镇涛 (米镇涛.) [4] | 许锡恩 (许锡恩.) [5]

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PKU CSCD

Abstract:

The influences of temperature, pressure, catalyst content, H2O2 content and mol ratio of propylene to H2O2 on epoxidation of propylene with H2O2 over TS-1 in a small-scale three phase loop thermosphonic reactor were investigated. The proper reaction condition was determined as follows: mol ratio of propylene to H2O2 was 1.1—1.3, temperature was 30—45?℃, reaction temperature rise was below 15?℃, pressure was 0—0.1?MPa, catalyst content was 3%—6%,and H2O2 content was 3%—5%.The conversion of H2O2 is above 94%,and selectivity of propylene is up to 96%. At these conditions, the yield of PO is higher than a figure of about 80%,which is achieved using conventional reactor. This reactor can realize catalyst regeneration continuously. This viable reactor can also be applied in other oxidation processes using TS-1, i.e. hydroxylation of phenol, ammoxidation of cyclohexanone.The results will lay a foundation for the development of the reactor in propylene epoxidation process.

Keyword:

丙烯 热虹吸环流反应器 环氧化 过氧化氢

Community:

  • [ 1 ] [陈晓晖]天津大学
  • [ 2 ] [李世军]天津大学
  • [ 3 ] [陈宪]福州大学
  • [ 4 ] [米镇涛]天津大学
  • [ 5 ] [许锡恩]天津大学

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Source :

化工学报

ISSN: 0438-1157

CN: 11-1946/TQ

Year: 2001

Issue: 1

Volume: 52

Page: 84-87

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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