Synthesis and characteristics of a new three-dimensional molybdoantimonate Na4Sb12Mo5O35 - Details

author：

Yongjing, W. (Yongjing, W..) ^[1] | Hanhui, Z. (Hanhui, Z..) ^[2] | Ruiqing, S. (Ruiqing, S..) ^[3] | Changcang, H. (Changcang, H..) ^[4] | Xiaohong, Y. (Xiaohong, Y..) ^[5]

Indexed by：

Scopus

Abstract：

A　novel　three-dimensional　compound　of　Na4Sb12Mo　5O35　has　been　synthesized　by　hydrothermal　methods　and　structurally　characterized　by　X-ray　crystallography.　It　crystallizes　in　the　triclinic　system　space　group　P1̄　with　a=11.574(2)Å,　b=12.594(3)Å,　c=13.277(3)Å,　α=94.59(3)°,　β=112.68(3)°,　γ=92.97(3)°,　V=1772.7(6)Å3,　Z=2,　R　1=0.0275,　wR2=0.0984　for　7364　unique　reflections　with　I>2σ(I).　The　molecular　structure　is　built　up　of　Mo6O　21,　MoO4　units,　and　cage-like　units　that　contain　12　Sb　atoms.　IR,　UV-Vis　DRIS　(Ultraviolet-Visible　Diffuse　Reflection　Integral　Spectrum),　fluorescent　spectra,　and　the　thermogravimetric　analysis　of　this　compound　were　investigated.　©　2005　Elsevier　Inc.　All　rights　reserved.

Keyword：

Crystal structure; Hydrothermal synthesis; Molybdoantimonate; Photoluminescence

Community：

[ 1 ] [Yongjing, W.]Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China
[ 2 ] [Yongjing, W.]State Key Lab. of Struct. Chemistry, Fuzhou University, Chinese Academy of Sciences, Fuzhou City, Fujian Province 350002, China
[ 3 ] [Hanhui, Z.]Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China
[ 4 ] [Hanhui, Z.]State Key Lab. of Struct. Chemistry, Fuzhou University, Chinese Academy of Sciences, Fuzhou City, Fujian Province 350002, China
[ 5 ] [Hanhui, Z.]Department of Chemistry, Fuzhou University, Chinese Academy of Sciences, Number 155, Yangqaio Road, Fuzhou City, Fujian Province 350002, China
[ 6 ] [Ruiqing, S.]Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China
[ 7 ] [Changcang, H.]Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China
[ 8 ] [Xiaohong, Y.]Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China

Reprint 's Address：

[Hanhui, Z.]Department of Chemistry, Fuzhou University, Chinese Academy of Sciences, Number 155, Yangqaio Road, Fuzhou City, Fujian Province 350002, China

Email：

hhzhang@fzu.edu.cn

Show more details

Related Keywords：

Source ：

Journal of Solid State Chemistry

ISSN： 0022-4596

Year： 2005

Issue： 3

Volume： 178

Page： 902-907

1 . 7 2 5

JCR@2005

3 . 2 0 0

JCR@2023

JCR Journal Grade：2

Cited Count：

WoS CC Cited Count：

SCOPUS Cited Count： 4

ESI Highly Cited Papers on the List： 0 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 5

Affiliated Colleges：

Get Fulltext

DOI Library Discovery Baidu Scholar Search SCOPUS

Type
Departments

All Years Choose Year From to