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author:

Guo, Y. (Guo, Y..) [1] | Wu, T. (Wu, T..) [2] | Zhang, M. (Zhang, M..) [3]

Indexed by:

Scopus

Abstract:

The current and potential distributions on the large-sized flat positive plate of lead-acid batteries in its formation have been studied by an in situ electrochemical scan technique. The formation can be divided into three stages. The first is before 15% charge amount At this stage, the conductivity of the positive paste is dominant. At the second stage, from about 15 to 62% charge, the formation rate depends on both the electrochemical reactions and ohmic polarization. At the final stage, the electrochemical reactions are a rate-limiting step. At the beginning of the formation, the distributions of the potential, current and polarization resistance are uneven, depending on the evolution of the conductive PbO2 zones. In comparison with the tubular positive plate, the distributions of potential and current are more uniform in the formation of the flat positive plate and the polarization is much smaller. The violent oxygen bubble evolution at the beginning will result in high contact resistance of local active mass. © 2005 The Electrochemical Society. All rights reserved.

Keyword:

Community:

  • [ 1 ] [Guo, Y.]Coll. of Chem. and Chem. Engineering, Fuzhou University, Fuzhou 350002, China
  • [ 2 ] [Wu, T.]Zibo Storage Battery Factory, Zibo, 255056, China
  • [ 3 ] [Zhang, M.]Zibo Storage Battery Factory, Zibo, 255056, China

Reprint 's Address:

  • [Guo, Y.]Coll. of Chem. and Chem. Engineering, Fuzhou University, Fuzhou 350002, China

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Source :

Journal of the Electrochemical Society

ISSN: 0013-4651

Year: 2005

Issue: 2

Volume: 152

Page: A415-A420

2 . 1 9

JCR@2005

3 . 1 0 0

JCR@2023

JCR Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 2

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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