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author:

Lai, G. (Lai, G..) [1] | Li, X. (Li, X..) [2] | Zhang, W. (Zhang, W..) [3] | Chen, C. (Chen, C..) [4]

Indexed by:

Scopus PKU CSCD

Abstract:

The polymerization was found quite stable by using two-stage monomer dropping method to prepare polyacrylate micro-latexes compared to the batch feeding and monomer pre-emulsification method. When the pre-adding fraction of monomer was less than 30%, the polymerization could be carried out stably and a final micro-latex with 65% transparency was obtained. When the fraction of polyacrylate in micro-latex prepared was over 34%, the micro-latexes appeared gelatiniform. Latex shearing with ammonia was investigated. It was found that a micro-latex with both better transparency (~65%) and lower viscosity (~220 cp) could be obtained when adding appropriate amount of ammonia during shearing. As a result, a micro-latex with small particles size (~63 nm) and narrow size distribution (1.17) was prepared by combining emulsion polymerization with two-stage monomer dropping and latex shearing in the presence of ammonia, which contained 32% polymer and only 1.2% emulsifier.

Keyword:

Acrylate; Ammonification; Emulsion polymerization; Micro-latex; Shearing

Community:

  • [ 1 ] [Lai, G.]School of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350002, China
  • [ 2 ] [Li, X.]School of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350002, China
  • [ 3 ] [Zhang, W.]School of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350002, China
  • [ 4 ] [Chen, C.]School of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350002, China

Reprint 's Address:

  • [Lai, G.]School of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350002, China

Email:

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Source :

Ion Exchange and Adsorption

ISSN: 1001-5493

Year: 2005

Issue: 5

Volume: 21

Page: 474-480

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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