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author:

Lin, R. (Lin, R..) [1] | Zhang, J. (Zhang, J..) [2]

Indexed by:

Scopus PKU CSCD

Abstract:

Using sodium carbonate as catalyst, carbon dioxide gasification kinetics for four kinds of low activity anthracites (Vad=2.69%-4.35%) was investigated with isothermal thermo-gravimetric analysis under ambient pressure. The reaction control conditions, eliminating both inner and outer diffusion effects, were examined. The relationships of coal conversion versus reaction time for these low activity anthracites were measured from 750°C to 950°C. The shrinkingcore model (SCM), homogeneous model (HM) and modification volumetric model (MVM) were used to correlate the relationships between conversion and time and to obtain the reaction rate constants at different temperatures. Then the reaction activation energy and the pre-exponential factor of four anthracites were predicted respectively by using the Arrhenius equation. According to the order of reaction rate constant determined by the above three models (SCM, HM, MVM), the activity order of the four anthracites was Shangjing coal>Yong'an Jiashai coal>Yong'an Fengshai coal>Yongding coal. The activation energy, ranging from 122.27-214.72 kJ·mol-1 estimated by this study, agreed well with the literature reported for the case of potassium chloride catalytic gasification by carbon dioxide for higher activity coals.

Keyword:

Isothermal thermo-gravimetric analysis; Low activity anthracites; Reaction kinetics; Sodium carbonate and carbon dioxide catalytic gasification

Community:

  • [ 1 ] [Lin, R.]Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
  • [ 2 ] [Zhang, J.]Institute of Chemical Engineering and Technology, Fuzhou University, Fuzhou 350002, China

Reprint 's Address:

  • [Lin, R.]Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China

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Source :

Journal of Chemical Industry and Engineering (China)

ISSN: 0438-1157

Year: 2005

Issue: 12

Volume: 56

Page: 2332-2341

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 8

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