Synthesis, structure and optical limiting effect of a novel inorganic-organic hybrid polymer containing mixed chains of copper(I)/iodine - Details

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Abstract：

In　this　paper,　treatment　of　N-ethyl-benzo[f]quinolium　(ebq)　iodide　and　CuI　with　excess　KI　afforded　an　unusual　coordination　polymer　[(ebq)2(Cu3I4)(CuI2)]n　(1).　1　crystallizes　in　tetragonal　system,　space　group　P4(2)bc　with　cell　parameters　of　a　=　23.2040　(　6　)　Å,　c　=　6.7393　(　3　)　Å,　V　=　3628.6　(　2　)　Å3,　Z　=　8,　Dc　=　2.622　g　/　c3,　R1　=　0.0447　and　w　R2　=　0.0974.　A　highly　interesting　feature　of　1　is　its　presence　of　mixed　types　of　chains　[　(　Cu3　I4　)n-　and　(　CuI2　)n-　chain]　in　one　crystal　lattice　based　on　supramolecular　self-assembly　directed　by　cations.　The　infinite　chains　(　Cu3　I4　)n-　and　(　CuI2　)n-　in　1　could　be　described　as　the　edge-sharing　arrangement　of　CuI4　tetrahedron.　Furthermore,　IR,　EA,　UV-Vis,　thermal　analysis　and　optical　limiting　measurements　were　adopted　to　characterize　polymer　1.　The　optical　limiting　experiment　shows　that　the　present　polymer　exhibits　a　large　optical　limiting　capacity.　©　2006　Elsevier　Inc.　All　rights　reserved.

Keyword：

Coordination polymers; copper(I) iodide; optical limiting effect; organic-inorganic hybrid

Community：

[ 1 ] [Li, H.-H.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350002, China
[ 2 ] [Chen, Z.-R.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350002, China
[ 3 ] [Li, J.-Q.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350002, China
[ 4 ] [Li, J.-Q.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Science, Fujian Fuzhou, 350002, China
[ 5 ] [Zhan, H.-B.]College of Materials Science and Engineering, Fuzhou University, Fuzhou, Fujian 350002, China
[ 6 ] [Zhang, W.-X.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350002, China
[ 7 ] [Huang, C.-C.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350002, China
[ 8 ] [Ma, C.]Department of Materials Science and Engineering, Tsinghua University, Beijing, 100084, China
[ 9 ] [Zhao, B.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350002, China

Reprint 's Address：

[Chen, Z.-R.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350002, China

Email：

czrfzu@163.com

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Source ：

Journal of Solid State Chemistry

ISSN： 0022-4596

Year： 2006

Issue： 5

Volume： 179

Page： 1415-1420

2 . 1 0 7

JCR@2006

3 . 2 0 0

JCR@2023

JCR Journal Grade：2

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SCOPUS Cited Count： 20

ESI Highly Cited Papers on the List： 0 Unfold All

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30 Days PV： 0

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