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author:

Dai, Y.-M. (Dai, Y.-M..) [1] | Tang, E. (Tang, E..) [2] | Li, Z.-J. (Li, Z.-J..) [3] | Wang, X.-Q. (Wang, X.-Q..) [4] | Yin, P.-X. (Yin, P.-X..) [5] | Yao, Y.-G. (Yao, Y.-G..) [6]

Indexed by:

Scopus PKU CSCD

Abstract:

The title compound, [Co(C7N2H7O 2)2]n·nH2O 1, was synthesized via the hydrothermal reaction of Co(OAc)2 with 3,5-diaminobenzoic acid and characterized by elemental analysis and infrared spectra. The crystal crystallizes in the monoclinic system, space group P21/c with a = 7.456(3), b = 9.972(3), c = 10.391(3) Å, β = 106.435(2)°, V = 741.0(4) Å3, Z = 2, C14H16CoN 4O5, Mr = 379.24, Dc = 1.700 g/cm3, F(000) = 390 and μ(MoKα) = 1.194 mm-1. The final R = 0.0324 and wR = 0.0886 for 1516 observed reflections with I > 2σ(I) and R = 0.0337 and wR = 0.0899 for all data. X-ray diffraction studies reveal that the title compound has an interesting 3D microporous architecture with guest water molecules inside the channel. Each Co atom, adopting a distorted octahedral geometry, is coordinated by two O atoms from two 3,5-diaminobenzoate ligands and four N atoms from four symmetry-related 3,5-diaminobenzoate ligands.

Keyword:

3,5-diaminobenzoic acid; Co(II) complex; Crystal structure; Hydrothermal reaction

Community:

  • [ 1 ] [Dai, Y.-M.]College of Chemistry and Material Science, Fujian Normal University, Fuzhou 350007, China
  • [ 2 ] [Dai, Y.-M.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
  • [ 3 ] [Dai, Y.-M.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350002, China
  • [ 4 ] [Tang, E.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
  • [ 5 ] [Li, Z.-J.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
  • [ 6 ] [Wang, X.-Q.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
  • [ 7 ] [Yin, P.-X.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
  • [ 8 ] [Yao, Y.-G.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China

Reprint 's Address:

  • [Yao, Y.-G.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China

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Source :

Jiegou Huaxue

ISSN: 0254-5861

CN: 35-1112/TQ

Year: 2006

Issue: 8

Volume: 25

Page: 971-974

0 . 7 2 9

JCR@2006

5 . 9 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:4

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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