Synthesis, structure, and spectroscopic properties of octa(iso-pentoxy) phthalocyaninatometal complexes - Details

author：

Lin, M.-J. (Lin, M.-J..) ^[1] | Wang, J.-D. (Wang, J.-D..) ^[2] | Chen, N.-S. (Chen, N.-S..) ^[3] | Huang, J.-L. (Huang, J.-L..) ^[4]

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Abstract：

A　series　of　octa-substituted　metal　phthalocyanines　[MPc(OC　5H11)8]　(M　=　Co,　Ni,　Cu,　Zn,　Pc　=　phthalocyaninato,　(OC5H11)8　=　iso-pentoxy)　were　obtained　from　condensation　of　isopentoxy　phthalonitrile　in　the　presence　of　DBU　in　n-pentanol.　The　compounds　were　characterized　using　elemental　analysis,　IR,　and　UV/Vis　spectra.　The　crystal　structures　of　all　compounds　except　M　=　Zn　were　determined　by　X-ray　diffraction　methods.　It　was　found　that　the　distortion　of　Pc　skeleton　come　of　not　only　the　intramolecular　steric　congestion　of　bulky　substituents,　but　also　the　slipped　overlaps　of　the　closest　molecules.　The　relations　of　some　bond　lengths　of　the　Pc＇s　skeleton　to　the　substituents　and　central　metal　atom,　as　well　as　the　spectroscopic　properties　are　discussed.　©　2006　Wiley-VCH　Verlag　GmbH　&　Co.　KGaA.

Keyword：

Crystal structures; IR; Metal phthalocyanines (substituted); UV-VIS spectra

Community：

[ 1 ] [Lin, M.-J.]College of Chemistry and Chemical Engineering, Fuzhou University, State Key Laboratory of Structural Chemistry, Fuzhou, China
[ 2 ] [Lin, M.-J.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350002, China
[ 3 ] [Wang, J.-D.]College of Chemistry and Chemical Engineering, Fuzhou University, State Key Laboratory of Structural Chemistry, Fuzhou, China
[ 4 ] [Chen, N.-S.]College of Chemistry and Chemical Engineering, Fuzhou University, State Key Laboratory of Structural Chemistry, Fuzhou, China
[ 5 ] [Huang, J.-L.]College of Chemistry and Chemical Engineering, Fuzhou University, State Key Laboratory of Structural Chemistry, Fuzhou, China

Reprint 's Address：

[Chen, N.-S.]College of Chemistry and Chemical Engineering, Fuzhou University, State Key Laboratory of Structural Chemistry, Fuzhou, China

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Source ：

Zeitschrift fur Anorganische und Allgemeine Chemie

ISSN： 0044-2313

Year： 2006

Issue： 14

Volume： 632

Page： 2315-2320

1 . 2 4 1

JCR@2006

1 . 1 0 0

JCR@2023

JCR Journal Grade：3

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SCOPUS Cited Count： 8

ESI Highly Cited Papers on the List： 0 Unfold All

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30 Days PV： 2

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