Fluorescence spectra and photo-generating rate of singlet oxygen of phthalocyaninatopalladium - Details

author：

Xu, X.-Z. (Xu, X.-Z..) ^[1] | Wang, J.-D. (Wang, J.-D..) ^[2] | Fang, X. (Fang, X..) ^[3] | Chen, N.-S. (Chen, N.-S..) ^[4] | Huang, J.-L. (Huang, J.-L..) ^[5]

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Abstract：

The　absorption　spectral　properties,　fluorescence　spectral　properties　and　the　abilities　of　photo-generating　singlet　oxygen　of　four　phthalocyanines,　namely　tetra-a-(2,2,4-trimethyl-3-pentoxy)　phthalocyaninatopalladium　(zinc)　and　tetra-α-(2,4-diterbu-tylphenoxy)　phthalocyaninatopalladium　(zinc),　were　determined.　Experimental　results　show　that　the　ability　of　photo-generating　singlet　oxygen　of　phthalocyaninatopalladium　is　similar　to　that　of　phthalocyaninatozincx,　though　palladium　(II)　is　an　open　shell　electron　structure　and　zinc(II)　is　a　closed　shell　structure.　This　may　be　concerned　with　a　weak　fluorescence　intensity　and　a　strong　inter-crossing　transition　of　phthalocyaninatopalladium.

Keyword：

Fluorescence spectra; Phthalocyaninatopalladium; Singlet oxygen

Community：

[ 1 ] [Xu, X.-Z.]Institute of Research on Functional Materials, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350002, China
[ 2 ] [Wang, J.-D.]Institute of Research on Functional Materials, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350002, China
[ 3 ] [Fang, X.]Institute of Research on Functional Materials, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350002, China
[ 4 ] [Chen, N.-S.]Institute of Research on Functional Materials, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350002, China
[ 5 ] [Huang, J.-L.]Institute of Research on Functional Materials, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350002, China

Reprint 's Address：

[Xu, X.-Z.]Institute of Research on Functional Materials, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350002, China

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Source ：

Spectroscopy and Spectral Analysis

ISSN： 1000-0593

Year： 2006

Issue： 12

Volume： 26

Page： 2280-2282

0 . 6 6 6

JCR@2006

0 . 7 0 0

JCR@2023

JCR Journal Grade：4

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ESI Highly Cited Papers on the List： 0 Unfold All

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30 Days PV： 1

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