Synthesis and characterization of organically templated copper halides with zero and one-dimensional hybrid structures: (nbq)4Cu 4I8 and [(ipq)2(Cu5I 7)]n - Details

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Abstract：

Two　new　organically　templated　copper　halides,　(nbq)4Cu　4I8　(1)　and　[(ipq)2(Cu5I　7)]　n　(2)　have　been　synthesized　in　the　presence　of　nbq+　and　ibq+　(nbq+　=　N-(n-butyl)-quinolinium,　ibq+　=　N-(iso-pentyl)-quinolinium)　acting　as　structure-directing　agents(SDAs).　Both　of　the　compounds　present　hybrid　structures　with　SDAs　and　inorganic　moieties　being　incorporated.　In　1,　tetrameric　Cu4I　8　4-　anion　is　composed　by　edge-sharing　CuI4　tetrahedrons　and　CuI3　planar　triangles.　But　the　inorganic　framework　of　2　presents　one-dimensional　arrangement　which　results　from　the　tetrahedron　CuI4　and　pseudo　trigonal　pyramid　CuI3　through　edge-sharing　fashion.　Electrostatic　interactions　between　organic　counter　cations　and　inorganic　moieties　could　be　observed　and　contribute　to　the　crystal　packing.　Both　compounds　are　further　characterized　by　IR,　UV-Vis,　elemental　analysis,　fluorescence　and　cyclic　voltammetry.　©　2007　Springer　Science+Business　Media,　LLC.

Keyword：

Coordination polymers; Copper iodide; Cyclic voltammetry; Organic-inorganic hybrid

Community：

[ 1 ] [Li, H.-H.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350002, China
[ 2 ] [Chen, Z.-R.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350002, China
[ 3 ] [Liu, Y.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350002, China
[ 4 ] [Ding, K.-N.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350002, China
[ 5 ] [Li, J.-Q.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350002, China
[ 6 ] [Li, J.-Q.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Science, Fuzhou, Fujian 350002, China
[ 7 ] [Huang, C.-C.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350002, China
[ 8 ] [Guo, L.-Q.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350002, China

Reprint 's Address：

[Chen, Z.-R.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350002, China

Email：

zrchen@fzu.edu.cn

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Source ：

Journal of Cluster Science

ISSN： 1040-7278

Year： 2007

Issue： 4

Volume： 18

Page： 817-829

0 . 8 8 6

JCR@2007

2 . 7 0 0

JCR@2023

JCR Journal Grade：3

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SCOPUS Cited Count： 12

ESI Highly Cited Papers on the List： 0 Unfold All

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30 Days PV： 0

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