Mild copper-catalyzed trifluoromethylation of terminal alkynes using an electrophilic trifluoromethylating reagent - Details

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Abstract：

A　catalytic　process　for　trifluoromethylation　of　terminal　alkynes　with　Togni＇s　reagent　has　been　developed,　affording　trifluoromethylated　acetylenes　in　good　to　excellent　yields.　The　reaction　is　conducted　at　room　temperature　and　exhibits　tolerance　to　a　range　of　functional　groups.　©　2012　Elsevier　Ltd.　All　rights　reserved.

Keyword：

Copper catalyst; Terminal alkyne; Trifluoromethylation reaction

Community：

[ 1 ] [Weng, Z.]Department of Chemistry, Fuzhou University, Fujian 350108, China
[ 2 ] [Li, H.]KAUST Catalysis Centre, Division of Chemicals and Life Sciences and Engineering, King Abdullah University of Science and Technology, Thuwal 23955-6900, Saudi Arabia
[ 3 ] [He, W.]Department of Chemistry, Fuzhou University, Fujian 350108, China
[ 4 ] [Yao, L.-F.]KAUST Catalysis Centre, Division of Chemicals and Life Sciences and Engineering, King Abdullah University of Science and Technology, Thuwal 23955-6900, Saudi Arabia
[ 5 ] [Tan, J.]Department of Chemistry, Fuzhou University, Fujian 350108, China
[ 6 ] [Chen, J.]Department of Chemistry, Fuzhou University, Fujian 350108, China
[ 7 ] [Yuan, Y.]Department of Chemistry, Fuzhou University, Fujian 350108, China
[ 8 ] [Huang, K.-W.]KAUST Catalysis Centre, Division of Chemicals and Life Sciences and Engineering, King Abdullah University of Science and Technology, Thuwal 23955-6900, Saudi Arabia

Reprint 's Address：

[Weng, Z.]Department of Chemistry, Fuzhou University, Fujian 350108, China

Email：

zweng@fzu.edu.cn

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Source ：

Tetrahedron

ISSN： 0040-4020

Year： 2012

Issue： 11

Volume： 68

Page： 2527-2531

2 . 8 0 3

JCR@2012

2 . 1 0 0

JCR@2023

JCR Journal Grade：2

CAS Journal Grade：3

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WoS CC Cited Count：

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ESI Highly Cited Papers on the List： 0 Unfold All

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30 Days PV： 0

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