Incorporating rare earth metal complexes and conjugated organic cations into polymeric iodoargentate: Structures and properties of two hybrid iodoargentates - Details

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Abstract：

Two　new　polymeric　iodoargentate　hybrids　induced　by　rare　earth　metal　complexes　and　conjugated　organic　cations,　{[Er(DMF)　8][Ag　6I　9]}　n　(1)　and　[(MMP)(AgI　2)]　n　(2)　(MMP　=　1-methyl-4-methylpyridinium)　were　obtained　by　the　routine　synthetic　reaction　and　structurally　determined.　In　compound　1,　a　(Ag　6I　9)　n　3n-　chain　is　defined　by　edge-sharing　Ag　6I　12　units,　and　in　2,　the　(Ag　2I　4)　n　2-　chains　are　constructed　by　edge-sharing　AgI　4　tetrahedra.　C-H⋯I　hydrogen　bonds　between　cations　and　iodoargentate　polyanions　contribute　to　their　structural　extension　from　1D　to　a　2D　layer　(for　1)　and　a　3D　network　(for　2).　The　UV/Vis　spectra　indicate　that　compared　with　2,　compound　1　exhibits　a　narrower　adsorption　scope　with　an　onset　at　about　360　nm,　and　it　has　a　much　wider　bandgap　of　about　3.50　eV.　Copyright　©　2012　WILEY-VCH　Verlag　GmbH　&　Co.　KGaA,　Weinheim.

Keyword：

Organic-inorganic hybrid composites; Iodoargentates; Absorption spectroscopy; Rare earths

Community：

[ 1 ] [Li, H.-H.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian, 350108, China
[ 2 ] [Li, H.-H.]State Key Laboratory Breeding Base of Photocatalysis, Fuzhou University, Fuzhou, 350002, China
[ 3 ] [Huang, S.-W.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian, 350108, China
[ 4 ] [Lian, Z.-X.]School of Chemistry and Chemical Engineering, Henan Institute of Science and Technology, Xinxiang, 453003, China
[ 5 ] [Liu, J.-B.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian, 350108, China
[ 6 ] [Wang, M.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian, 350108, China
[ 7 ] [Chen, Z.-R.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian, 350108, China
[ 8 ] [Chen, Z.-R.]State Key Laboratory Breeding Base of Photocatalysis, Fuzhou University, Fuzhou, 350002, China

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[Li, H.-H.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian, 350108, China

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Zeitschrift fur Anorganische und Allgemeine Chemie

ISSN： 0044-2313

Year： 2012

Issue： 5

Volume： 638

Page： 851-855

1 . 1 6 3

JCR@2012

1 . 1 0 0

JCR@2023

JCR Journal Grade：3

CAS Journal Grade：4

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WoS CC Cited Count：

SCOPUS Cited Count： 28

ESI Highly Cited Papers on the List： 0 Unfold All

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Chinese Cited Count：

30 Days PV： 1

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