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Abstract:
The performance of dye-sensitized ZnO solar cells was improved by a facile surface-treatment approach through chemical-bath deposition. After the surface treatment, the quantum dots of Zn 2SnO 4 were deposited onto ZnO nanoparticles accompanied by the aggregations of Zn 2SnO 4 nanoparticles. The ZnO film displayed a better resistance to acidic dye solution on account of the deposited Zn 2SnO 4 nanoparticles. Meanwhile, the open-circuit photovoltage was greatly enhanced, which can be ascribed to the increased conduction-band edge of ZnO and inhibited interfacial charge recombination. Although the deposition of Zn 2SnO 4 decreased the adsorption amounts of N719 dye, the aggregates of Zn 2SnO 4 with a size of 350-450 nm acted as the effective light-scattering layer, thereby resulting in an improved short-circuit photocurrent. By co-sensitizing 10 μm-thick ZnO film with N719 and D131 dyes, a top efficiency of 4.38 % was achieved under the illumination of one sun (AM 1.5, 100 mW cm -2).Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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Chemistry - A European Journal
ISSN: 0947-6539
Year: 2012
Issue: 37
Volume: 18
Page: 11716-11722
5 . 8 3 1
JCR@2012
3 . 9 0 0
JCR@2023
JCR Journal Grade:1
CAS Journal Grade:2
Cited Count:
SCOPUS Cited Count: 28
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
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30 Days PV: 0
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