Synthesis, structure and luminescence of a hydrogen-bonding helical-chain Cu(II) compound based on (8-quinolinyloxy)acetate - Details

author：

Liu, D.-S. (Liu, D.-S..) ^[1] | Sui, Y. (Sui, Y..) ^[2] | Chen, W.-T. (Chen, W.-T..) ^[3] | Chen, J.-Z. (Chen, J.-Z..) ^[4] | Huang, C.-C. (Huang, C.-C..) ^[5]

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Abstract：

A　new　compound　of　CuCl(QOA)(H2O)　(1)　[QOA　=　(8-quinolinyloxy)　acetate]　has　been　prepared　and　characterized　by　elemental　analysis,　IR　spectroscopy　and　single-crystal　X-ray　diffraction.　The　crystal　is　of　orthorhombic,　space　group　P212121　with　a　=　5.364(1)　Å　,　b　=　13.876(3)　Å　,　c　=　15.435(3)　Å　,　V　=　1,148.8(4)　Å　3,　Mr　=　319.19,　Dc　=　1.846　g　cm-3,　Z　=　4,　F(000)　=　644,　l　=　2.138　mm-1,　flack　parameter　=　0.00(17),　the　final　R　=　0.0311　and　wR　=　0.0646　for　2,179　observed　reflections　(I[2r(I)).　Compound　1　consists　of　one-dimensional　helical　chains　deriving　from　CuCl(QOA)(H2O)　units　linked　by　hydrogen　bonds　and　further　extend　into　a　3D　supramolecular　structure　through　Van　der　Waals　interactions,　and　it　exhibits　strong　luminescent　emission　at　room　temperature.　©　Iranian　Chemical　Society　2012.

Keyword：

(8-quinolinyloxy)acetate; Crystal structure; CuII compound; Luminescence

Community：

[ 1 ] [Liu, D.-S.]School of Chemistry and Chemical Engineering, Institute of Applied Chemistry, JingGangShan University, Ji'an, Jiangxi 343009, China
[ 2 ] [Liu, D.-S.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350108, China
[ 3 ] [Sui, Y.]School of Chemistry and Chemical Engineering, Institute of Applied Chemistry, JingGangShan University, Ji'an, Jiangxi 343009, China
[ 4 ] [Chen, W.-T.]School of Chemistry and Chemical Engineering, Institute of Applied Chemistry, JingGangShan University, Ji'an, Jiangxi 343009, China
[ 5 ] [Chen, J.-Z.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350108, China
[ 6 ] [Huang, C.-C.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350108, China

Reprint 's Address：

[Liu, D.-S.]School of Chemistry and Chemical Engineering, Institute of Applied Chemistry, JingGangShan University, Ji'an, Jiangxi 343009, China

Email：

d.s.liu@hotmail.com

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Source ：

Journal of the Iranian Chemical Society

ISSN： 1735-207X

Year： 2012

Issue： 5

Volume： 9

Page： 827-831

1 . 4 6 7

JCR@2012

2 . 2 0 0

JCR@2023

JCR Journal Grade：2

CAS Journal Grade：4

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SCOPUS Cited Count：

ESI Highly Cited Papers on the List： 0 Unfold All

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Chinese Cited Count：

30 Days PV： 1

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