Room-temperature base-free copper-catalyzed trifluoromethylation of organotrifluoroborates to trifluoromethylarenes - Details

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Abstract：

An　efficient　room　temperature　copper-catalyzed　trifluoromethylation　of　organotrifluoroborates　under　the　base　free　condition　using　an　electrophilic　trifluoromethylating　reagent　is　demonstrated.　The　corresponding　trifluoromethylarenes　were　obtained　in　good　to　excellent　yields　and　the　reaction　tolerates　a　wide　range　of　functional　groups.　©　2012　Elsevier　Ltd.　All　rights　reserved.

Keyword：

Copper catalyst; Electrophilic trifluoromethylation reaction; Trifluoromethylarenes

Community：

[ 1 ] [Huang, Y.]Department of Chemistry, Fuzhou University, Fuzhou 350108, China
[ 2 ] [Huang, Y.]Fujian Provincial Key Laboratory of Photocatalysis, State Key Laboratory Breeding Base, Fuzhou University, Fuzhou 350002, China
[ 3 ] [Fang, X.]Department of Chemistry, Fuzhou University, Fuzhou 350108, China
[ 4 ] [Lin, X.]Department of Chemistry, Fuzhou University, Fuzhou 350108, China
[ 5 ] [Li, H.]King Abdullah University of Science and Technology (KAUST), Division of Chemical and Life Sciences and Engineering, KAUST Catalysis Center, Thuwal 23955-6900, Saudi Arabia
[ 6 ] [He, W.]Department of Chemistry, Fuzhou University, Fuzhou 350108, China
[ 7 ] [Huang, K.-W.]King Abdullah University of Science and Technology (KAUST), Division of Chemical and Life Sciences and Engineering, KAUST Catalysis Center, Thuwal 23955-6900, Saudi Arabia
[ 8 ] [Yuan, Y.]Department of Chemistry, Fuzhou University, Fuzhou 350108, China
[ 9 ] [Weng, Z.]Department of Chemistry, Fuzhou University, Fuzhou 350108, China
[ 10 ] [Weng, Z.]Fujian Provincial Key Laboratory of Photocatalysis, State Key Laboratory Breeding Base, Fuzhou University, Fuzhou 350002, China

Reprint 's Address：

[Huang, K.-W.]King Abdullah University of Science and Technology (KAUST), Division of Chemical and Life Sciences and Engineering, KAUST Catalysis Center, Thuwal 23955-6900, Saudi Arabia

Email：

hkw@kaust.edu.sa

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Source ：

Tetrahedron

ISSN： 0040-4020

Year： 2012

Issue： 48

Volume： 68

Page： 9949-9953

2 . 8 0 3

JCR@2012

2 . 1 0 0

JCR@2023

JCR Journal Grade：2

CAS Journal Grade：3

Cited Count：

WoS CC Cited Count：

SCOPUS Cited Count： 35

ESI Highly Cited Papers on the List： 0 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 0

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