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author:

Dai, H. (Dai, H..) [1] | Chen, Y. (Chen, Y..) [2] | Lin, Y. (Lin, Y..) [3] | Xu, G. (Xu, G..) [4] | Yang, C. (Yang, C..) [5] | Tong, Y. (Tong, Y..) [6] | Guo, L. (Guo, L..) [7] | Chen, G. (Chen, G..) [8]

Indexed by:

Scopus

Abstract:

In this paper, we propose a facile approach for palladium nanoparticles load using silicon carbide nanoparticles as the new supported matrix and a familiar NaBH4 as reducer. Detailed X-ray photoelectron spectrum (XPS) and transmission electron microscopy (TEM) analysis of the resultant products indicated that palladium nanoparticles are successfully immobilized onto the surface of the silicon carbide nanoparticles with uniform size distribution between 5 and 7 nm. The relative electrochemical characterization clearly demonstrated excellent electrocatalytic activity of this material toward alcohol in alkaline electrolytes. Investigation on the characteristics of the electrocatalytic activity of this material further indicated that the palladium nanoparticles supporting on SiC are very promising for direct alcohol fuel cells (DMFCs), biosensor and electronic devices. Moreover, it was proved that silicon carbide nanoparticles with outstanding properties as support for catalysis are of strong practical interest. And the silicon carbide could perform attractive role in adsorbents, electrodes, biomedical applications, etc. © 2012 Elsevier Ltd.

Keyword:

Electrocatalytic; Ethanol; Methanol; Palladium nanoparticles; Silicon carbide nanoparticles

Community:

  • [ 1 ] [Dai, H.]Ministry of Education Key Laboratory of Analysis and Detection for Food Safety, Fujian Provincial Key Laboratory of Analysis and Detection for Food Safety, Fuzhou University, Fuzhou, Fujian 350002, China
  • [ 2 ] [Dai, H.]College of Chemistry and Chemical Engineering, Fujian Normal University, Fuzhou, Fujian 350108, China
  • [ 3 ] [Chen, Y.]Ministry of Education Key Laboratory of Analysis and Detection for Food Safety, Fujian Provincial Key Laboratory of Analysis and Detection for Food Safety, Fuzhou University, Fuzhou, Fujian 350002, China
  • [ 4 ] [Lin, Y.]Ministry of Education Key Laboratory of Analysis and Detection for Food Safety, Fujian Provincial Key Laboratory of Analysis and Detection for Food Safety, Fuzhou University, Fuzhou, Fujian 350002, China
  • [ 5 ] [Lin, Y.]College of Chemistry and Chemical Engineering, Fujian Normal University, Fuzhou, Fujian 350108, China
  • [ 6 ] [Xu, G.]College of Chemistry and Chemical Engineering, Fujian Normal University, Fuzhou, Fujian 350108, China
  • [ 7 ] [Yang, C.]Ministry of Education Key Laboratory of Analysis and Detection for Food Safety, Fujian Provincial Key Laboratory of Analysis and Detection for Food Safety, Fuzhou University, Fuzhou, Fujian 350002, China
  • [ 8 ] [Yang, C.]Longyan Quality Inspection Institute of Product, Longyan, Fujian 364000, China
  • [ 9 ] [Tong, Y.]College of Chemistry and Chemical Engineering, Fujian Normal University, Fuzhou, Fujian 350108, China
  • [ 10 ] [Guo, L.]Ministry of Education Key Laboratory of Analysis and Detection for Food Safety, Fujian Provincial Key Laboratory of Analysis and Detection for Food Safety, Fuzhou University, Fuzhou, Fujian 350002, China
  • [ 11 ] [Chen, G.]Ministry of Education Key Laboratory of Analysis and Detection for Food Safety, Fujian Provincial Key Laboratory of Analysis and Detection for Food Safety, Fuzhou University, Fuzhou, Fujian 350002, China

Reprint 's Address:

  • [Dai, H.]College of Chemistry and Chemical Engineering, Fujian Normal University, Fuzhou, Fujian 350108, China

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Source :

Electrochimica Acta

ISSN: 0013-4686

Year: 2012

Volume: 85

Page: 644-649

3 . 7 7 7

JCR@2012

5 . 5 0 0

JCR@2023

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 18

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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