Copper-catalyzed trifluoromethylation of arylsulfinate salts using an electrophilic trifluoromethylation reagent - Details

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Abstract：

A　copper-catalyzed　method　for　the　trifluoromethylation　of　arylsulfinates　with　Togni＇s　reagent　has　been　developed,　affording　aryltrifluoromethylsulfones　in　moderate　to　good　yields.　A　wide　range　of　functional　groups　in　arylsulfinates　are　compatible　with　the　reaction　conditions.　©　2013　Elsevier　Ltd.　All　rights　reserved.

Keyword：

Aryltrifluoromethylsulphones; Copper catalyst; Electrophilic trifluoromethylation reaction

Community：

[ 1 ] [Lin, X.]Department of Chemistry, Fuzhou University, Fujian 350108, China
[ 2 ] [Lin, X.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
[ 3 ] [Wang, G.]Department of Chemistry, Fuzhou University, Fujian 350108, China
[ 4 ] [Li, H.]King Abdullah University of Science and Technology (KAUST), Division of Physical Sciences and Engineering, KAUST Catalysis Center, Thuwal 23955-6900, Saudi Arabia
[ 5 ] [Huang, Y.]Department of Chemistry, Fuzhou University, Fujian 350108, China
[ 6 ] [He, W.]Department of Chemistry, Fuzhou University, Fujian 350108, China
[ 7 ] [Ye, D.]Department of Chemistry, Fuzhou University, Fujian 350108, China
[ 8 ] [Huang, K.-W.]King Abdullah University of Science and Technology (KAUST), Division of Physical Sciences and Engineering, KAUST Catalysis Center, Thuwal 23955-6900, Saudi Arabia
[ 9 ] [Yuan, Y.]Department of Chemistry, Fuzhou University, Fujian 350108, China
[ 10 ] [Weng, Z.]Department of Chemistry, Fuzhou University, Fujian 350108, China
[ 11 ] [Weng, Z.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China

Reprint 's Address：

[Huang, K.-W.]King Abdullah University of Science and Technology (KAUST), Division of Physical Sciences and Engineering, KAUST Catalysis Center, Thuwal 23955-6900, Saudi Arabia

Email：

hkw@kaust.edu.sa

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Source ：

Tetrahedron

ISSN： 0040-4020

Year： 2013

Issue： 12

Volume： 69

Page： 2628-2632

2 . 8 1 7

JCR@2013

2 . 1 0 0

JCR@2023

JCR Journal Grade：2

CAS Journal Grade：3

Cited Count：

WoS CC Cited Count：

SCOPUS Cited Count： 31

ESI Highly Cited Papers on the List： 0 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 0

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