Room temperature nucleophilic trifluoromethylthiolation of benzyl bromides with (bpy)Cu(SCF3) - Details

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Abstract：

The　nucleophilic　trifluoromethylthiolation　of　benzyl　bromides　using　(bpy)Cu(SCF3)　gave　the　desired　products　of　benzyl　trifluoromethyl　sulfides　in　good　to　excellent　yields.　A　diverse　set　of　important　functional　groups　including　cyano,　nitro,　ester,　alkoxy,　halide,　and　heterocyclic　groups　can　be　well　tolerated　in　the　protocol.　©　2013　Elsevier　Ltd.　All　rights　reserved.

Keyword：

Benzyl bromides; Copper reagent; Trifluoromethylthiolation

Community：

[ 1 ] [Kong, D.]Department of Chemistry, Fuzhou University, Fujian 350108, China
[ 2 ] [Jiang, Z.]Department of Chemistry, Fuzhou University, Fujian 350108, China
[ 3 ] [Xin, S.]Department of Chemistry, Fuzhou University, Fujian 350108, China
[ 4 ] [Bai, Z.]Department of Chemistry, Fuzhou University, Fujian 350108, China
[ 5 ] [Yuan, Y.]Department of Chemistry, Fuzhou University, Fujian 350108, China
[ 6 ] [Weng, Z.]Department of Chemistry, Fuzhou University, Fujian 350108, China

Reprint 's Address：

[Weng, Z.]Department of Chemistry, Fuzhou University, Fujian 350108, China

Email：

zweng@fzu.edu.cn

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Source ：

Tetrahedron

ISSN： 0040-4020

Year： 2013

Issue： 30

Volume： 69

Page： 6046-6050

2 . 8 1 7

JCR@2013

2 . 1 0 0

JCR@2023

JCR Journal Grade：2

CAS Journal Grade：3

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SCOPUS Cited Count：

ESI Highly Cited Papers on the List： 0 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 1

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