Investigation on 1O2 generation ability of di-sulfonic phthalocyanine zinc isomers using an HPLC-CL system - Details

author：

Jiang, Z. (Jiang, Z..) ^[1] | Chen, M. (Chen, M..) ^[2] | Hu, Y. (Hu, Y..) ^[3] | Wang, J. (Wang, J..) ^[4] | Chen, G. (Chen, G..) ^[5]

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Scopus

Abstract：

An　HPLC　system　combining　a　chemiluminescence　detector　was　applied　to　estimate　the　singlet　oxygen　(1O2)　generation　ability　of　di-sulfonic　phthalocyanine　zinc　(ZnPcS2)　isomers.　As　photosensitizers,　ZnPcS2　produces　1O2　in　air-saturated　solutions　under　photoirradiation.　The　latter　reacts　with　methyl　Cypridina　luciferin　analogue　(MCLA)　to　initiate　chemiluminescence.　This　photoinduced　chemiluminescence　(PCL)　of　MCLA　provides　an　easy　method　for　evaluating　the　isomers＇　1O2　generation　ability　during　a　simultaneous　HPLC　separation　procedure.　The　cis-isomers　and　trans-isomers　of　ZnPcS2　show　different　1O2　generation　abilities,　which　are　in　accordance　with　differences　in　their　absorption　spectra.　Copyright　©　2013　John　Wiley　&　Sons,　Ltd.　Copyright　©　2013　John　Wiley　&　Sons,　Ltd.

Keyword：

di-sulfonic phthalocyanine zinc isomers; HPLC; methyl Cypridina luciferin analogue; photoinduced chemiluminescence; singlet oxygen generation

Community：

[ 1 ] [Jiang, Z.]Ministry of Education Key Laboratory of Analysis and Detection for Food Safety, Department of Chemistry, Fuzhou University Fujian, Fuzhou 350002, China
[ 2 ] [Chen, M.]Ministry of Education Key Laboratory of Analysis and Detection for Food Safety, Department of Chemistry, Fuzhou University Fujian, Fuzhou 350002, China
[ 3 ] [Hu, Y.]Ministry of Education Key Laboratory of Analysis and Detection for Food Safety, Department of Chemistry, Fuzhou University Fujian, Fuzhou 350002, China
[ 4 ] [Wang, J.]Ministry of Education Key Laboratory of Analysis and Detection for Food Safety, Department of Chemistry, Fuzhou University Fujian, Fuzhou 350002, China
[ 5 ] [Chen, G.]Ministry of Education Key Laboratory of Analysis and Detection for Food Safety, Department of Chemistry, Fuzhou University Fujian, Fuzhou 350002, China

Reprint 's Address：

[Chen, G.]Ministry of Education Key Laboratory of Analysis and Detection for Food Safety, Department of Chemistry, Fuzhou University Fujian, Fuzhou 350002, China

Email：

gnchen@fzu.edu.cn

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Source ：

Luminescence

ISSN： 1522-7235

Year： 2013

Issue： 6

Volume： 28

Page： 922-926

1 . 6 7 5

JCR@2013

3 . 2 0 0

JCR@2023

JCR Journal Grade：4

CAS Journal Grade：4

Cited Count：

WoS CC Cited Count：

SCOPUS Cited Count： 2

ESI Highly Cited Papers on the List： 0 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 1

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