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author:

Wu, W. (Wu, W..) [1] | Liang, S. (Liang, S..) [2] | Wang, X. (Wang, X..) [3] | Bi, J. (Bi, J..) [4] | Liu, P. (Liu, P..) [5] | Wu, L. (Wu, L..) [6]

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Scopus

Abstract:

Microcrystalline ABi2Nb2O9 (A=Sr, Ba) photocatalysts were successfully synthesized by a citrate complex method. The as-prepared samples were characterized by the X-ray diffraction technique, BET surface area analysis, UVvis diffuse reflectance spectrum, transmission electron microscopy, X-ray photoelectron spectroscopy and inductively coupled plasma-atomic emission spectrometry. The results indicated that single-phase orthorhombic SrBi2Nb2O9 could be obtained after being calcined above 650 °C, while BaBi2Nb2O 9 was tetragonal. Based on the diffuse reflectance spectra, the band gaps of the obtained samples were calculated to be around 3.343.54 eV. For the photocatalytic redox reaction of methyl orange under UV-light irradiation, SrBi2Nb2O9 exhibited higher photocatalytic activity than that of BaBi2Nb2O9. The effects of the crystallinities, BET surface areas and crystal structures of the samples on the photocatalytic activities were discussed in detail. © 2010 Elsevier Inc. All rights reserved.

Keyword:

ABi2Nb2O9 (A=Sr, Ba); Citrate complex; Microcrystalline; Photocatalysis

Community:

  • [ 1 ] [Wu, W.]State Key Laboratory Breeding Base of Photocatalysis, Research Institute of Photocatalysis, Fuzhou University, Fuzhou 350002, China
  • [ 2 ] [Liang, S.]State Key Laboratory Breeding Base of Photocatalysis, Research Institute of Photocatalysis, Fuzhou University, Fuzhou 350002, China
  • [ 3 ] [Wang, X.]State Key Laboratory Breeding Base of Photocatalysis, Research Institute of Photocatalysis, Fuzhou University, Fuzhou 350002, China
  • [ 4 ] [Bi, J.]State Key Laboratory Breeding Base of Photocatalysis, Research Institute of Photocatalysis, Fuzhou University, Fuzhou 350002, China
  • [ 5 ] [Liu, P.]State Key Laboratory Breeding Base of Photocatalysis, Research Institute of Photocatalysis, Fuzhou University, Fuzhou 350002, China
  • [ 6 ] [Wu, L.]State Key Laboratory Breeding Base of Photocatalysis, Research Institute of Photocatalysis, Fuzhou University, Fuzhou 350002, China

Reprint 's Address:

  • [Wu, L.]State Key Laboratory Breeding Base of Photocatalysis, Research Institute of Photocatalysis, Fuzhou University, Fuzhou 350002, China

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Source :

Journal of Solid State Chemistry

ISSN: 0022-4596

Year: 2011

Issue: 1

Volume: 184

Page: 81-88

2 . 1 5 9

JCR@2011

3 . 2 0 0

JCR@2023

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 38

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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