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Abstract:
Coal-tar pitch was modified with a lignin/silica hybrid (LSH) from rice husk, and carbonization behavior of the pitch-LSH mixtures and optical texture of resultant semi-cokes were studied in this paper. The carbonization behavior was characterized using TGA, FTIR, SEM and EDS. In addition, the optical texture of resultant semi-cokes was characterized by polarized-light microscopy. Results show that the LSH addition has great effect on the carbonization behavior of the pitch-LSH mixtures and the optical texture of resultant semi-cokes. The pitch-LSH mixtures have better thermal stability than coal-tar pitch, as indicated by that the initial weight loss temperature and carbonization yield of the pitch-LSH mixtures increase with increasing LSH content. There are more condensed polynuclear structures with high aromaticity in the resultant semi-cokes with increasing pyrolysis temperature. However, the LSH addition deteriorates the optical texture of resultant semi-cokes varying from coarse-grained mosaics to fine-grained mosaics. Furthermore, there exist a great many silica particles with size of less than 3 μm uniformly distributed in the pyrolysis product of the pitch-LSH mixture. © 2010 Elsevier B.V.
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Journal of Analytical and Applied Pyrolysis
ISSN: 0165-2370
Year: 2011
Issue: 1
Volume: 90
Page: 1-6
2 . 4 8 7
JCR@2011
5 . 8 0 0
JCR@2023
JCR Journal Grade:2
CAS Journal Grade:3
Cited Count:
SCOPUS Cited Count: 17
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 4
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