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author:

Lin, Q. (Lin, Q..) [1] | Tang, H. (Tang, H..) [2] | Li, C. (Li, C..) [3] | Wu, L. (Wu, L..) [4]

Indexed by:

Scopus

Abstract:

Coal-tar pitch was modified with a lignin/silica hybrid (LSH) from rice husk, and carbonization behavior of the pitch-LSH mixtures and optical texture of resultant semi-cokes were studied in this paper. The carbonization behavior was characterized using TGA, FTIR, SEM and EDS. In addition, the optical texture of resultant semi-cokes was characterized by polarized-light microscopy. Results show that the LSH addition has great effect on the carbonization behavior of the pitch-LSH mixtures and the optical texture of resultant semi-cokes. The pitch-LSH mixtures have better thermal stability than coal-tar pitch, as indicated by that the initial weight loss temperature and carbonization yield of the pitch-LSH mixtures increase with increasing LSH content. There are more condensed polynuclear structures with high aromaticity in the resultant semi-cokes with increasing pyrolysis temperature. However, the LSH addition deteriorates the optical texture of resultant semi-cokes varying from coarse-grained mosaics to fine-grained mosaics. Furthermore, there exist a great many silica particles with size of less than 3 μm uniformly distributed in the pyrolysis product of the pitch-LSH mixture. © 2010 Elsevier B.V.

Keyword:

Carbonization; Coal-tar pitch; Optical texture; Semi-coke; Thermal analysis

Community:

  • [ 1 ] [Lin, Q.]College of Materials Science and Engineering, Fuzhou University, Qi Shan Campus, 2 Xue Yuan Road, Fuzhou 350108, Fujian, China
  • [ 2 ] [Tang, H.]College of Materials Science and Engineering, Fuzhou University, Qi Shan Campus, 2 Xue Yuan Road, Fuzhou 350108, Fujian, China
  • [ 3 ] [Li, C.]College of Materials Science and Engineering, Fuzhou University, Qi Shan Campus, 2 Xue Yuan Road, Fuzhou 350108, Fujian, China
  • [ 4 ] [Wu, L.]College of Materials Science and Engineering, Fuzhou University, Qi Shan Campus, 2 Xue Yuan Road, Fuzhou 350108, Fujian, China

Reprint 's Address:

  • [Lin, Q.]College of Materials Science and Engineering, Fuzhou University, Qi Shan Campus, 2 Xue Yuan Road, Fuzhou 350108, Fujian, China

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Source :

Journal of Analytical and Applied Pyrolysis

ISSN: 0165-2370

Year: 2011

Issue: 1

Volume: 90

Page: 1-6

2 . 4 8 7

JCR@2011

5 . 8 0 0

JCR@2023

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 17

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 4

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