Unprecedented pseudo water tapes stabilized by a one-dimensional Cu(II) coordination polymer - Details

author：

Yang, E. (Yang, E..) ^[1] | Chen, S.-Y. (Chen, S.-Y..) ^[2] | Liu, Z.-S. (Liu, Z.-S..) ^[3] | Li, J.-Q. (Li, J.-Q..) ^[4]

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Scopus CSCD

Abstract：

A　new　compound,　[Cu(mal)(tmdpy)(H2O)].4H2O　(1,　H　2mal　=　malonic　acid,　tmdpy　=　4,4＇-trimethylenedipyridine)　has　been　synthesized　by　the　hydrothermal　synthesis　and　structurally　characterized　by　X-ray　crystallography.　It　crystallizes　in　triclinic,　space　group　P̄1　with　a　=　9.1662(6),　b　=　10.6266(7),　c　=　11.3056(7)　Å,　a　=　84.6390(10),　β　=　72.1030(10),　γ　=　73.0420(10)°,　V　=　1002.37(11)　Å3,　C16H26CuN2O9,　Mr　=　453.93,　Z　=　2,　Dc　=　1.504　g/cm3,　μ　=　1.140　mm　-1M,　F(000)　=　474,　R　=　0.0375　and　wR　=　0.0975　for　3187　observed　reflections　(I　>　2σ(I)).　In　the　structure　of　1,　the　tmdpy　ligands　link　the　[Cu(mal)(H2O)]　units　into　an　infinite　chain,　and　the　water　molecules　and　carboxylate　oxygen　donors　(O(2)　and　O(4))　from　the　mal　ligands　cooperatively　built　an　interesting　hydrogen　bonding　network　with　unprecedented　pseudo　water　tape　substructures.　Copyright　©　2008　Chinese　Journal　of　Structural　Chemistry.

Keyword：

Coordination polymer; Crystal structure; Hydrothermal synthesis; Water cluster

Community：

[ 1 ] [Yang, E.]Department of Chemistry, Fuzhou University, Fuzhou 350002, China
[ 2 ] [Yang, E.]College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, China
[ 3 ] [Chen, S.-Y.]College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, China
[ 4 ] [Liu, Z.-S.]College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, China
[ 5 ] [Li, J.-Q.]Department of Chemistry, Fuzhou University, Fuzhou 350002, China
[ 6 ] [Li, J.-Q.]Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China

Reprint 's Address：

杨娥
[Yang, E.]Department of Chemistry, Fuzhou University, Fuzhou 350002, China

Email：

yangeli66@yahoo.com.cn

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Source ：

Jiegou Huaxue

ISSN： 0254-5861

CN： 35-1112/TQ

Year： 2011

Issue： 1

Volume： 30

Page： 101-104

0 . 4 4

JCR@2011

5 . 9 0 0

JCR@2023

ESI Discipline： CHEMISTRY;

JCR Journal Grade：4

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ESI Highly Cited Papers on the List： 0 Unfold All

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30 Days PV： 1

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