In　this　paper,　the　nanobelts　of　molybdenum　oxide　amine　composite　were　successfully　synthesized　via　a　redox-assisted　molecular　assembly　route　under　the　hydrothermal　conditions.　The　synthesized　nanobelts　were　characterized　by　XRD,　SEM,　TEM,　TG　and　FT-IR　measurements.　The　thickness　of　nanobelts　is　found　to　be　ca.　20-30　nm　and　their　lengths　are　up　to　several　tens　of　micrometers.　Based　on　a　series　of　the　experimental　results,　a　possible　model,　redox-intercalation-　exfoliation,　was　suggested　for　the　formation　of　nanobelts　of　molybdenum　oxide　amine　composite.　©　2010　Published　by　Elsevier　B.V.