Synthesis, properties, and theoretical study of a cation-induced iodoargentate hybrid: [(PIP-H2)4·(Ag 4I12)·H2O]n - Details

author：

Lin, Z.-S. (Lin, Z.-S..) ^[1] | Dong, H.-J. (Dong, H.-J..) ^[2] | Wu, Y.-L. (Wu, Y.-L..) ^[3] | Li, H.-H. (Li, H.-H..) ^[4] | Chen, Z.-R. (Chen, Z.-R..) ^[5]

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Abstract：

A　new　cation-induced　hybrid　iodoargentate,　[(PIP-H2)　4·(Ag4I12)·H2O]　n　(1)　(PIP　=　piperazine)　has　been　obtained　by　the　routine　synthetic　reaction　in　DMF　solution　and　structurally　determined.　1　crystallizes　in　monoclinic　system,　space　group　P21/n　with　unit　cell　parameters:　a　=　12.718(3),　b　=　9.3861(19),　c　=　20.098(4)Å,　β　=　90.33(3)°,　V　=　2399.1(8)Å3,　Z　=　4,　C8H24Ag　2I6N4O,　Mr　=　1169.45,　Dc　=　3.238　g/cm3,　F(000)　=　2080,　μ(MoKα)　=　9.356mm　-1,　the　final　R1　=　0.0681　and　wR　=　0.1757　for　5255　observed　reflections　with　I　>　2σ(I).　In　1,　0-D　[Ag4I　12]8-　clusters　were　constructed　from　four　vertex-sharing　AgI4　tetrahedra　and　further　linked　by　hydrogen　bonds　to　give　a　2-D　layer.　Luminescence　can　be　detected　in　the　title　compound.　Quantum　chemistry　calculation　with　DFT　method　was　carried　out　to　reveal　its　electronic　structure.　Copyright　©　Taylor　&　Francis　Group,　LLC.

Keyword：

DFT calculation; iodoargentate; organic-inorganic hybrid

Community：

[ 1 ] [Lin, Z.-S.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350108, China
[ 2 ] [Dong, H.-J.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350108, China
[ 3 ] [Wu, Y.-L.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350108, China
[ 4 ] [Li, H.-H.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350108, China
[ 5 ] [Chen, Z.-R.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350108, China

Reprint 's Address：

[Li, H.-H.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350108, China

Email：

lihh@fzu.edu.cn

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Source ：

Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry

ISSN： 1553-3174

Year： 2011

Issue： 6

Volume： 41

Page： 583-589

0 . 4 6 7

JCR@2011

0 . 7 8 4

JCR@2018

JCR Journal Grade：4

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ESI Highly Cited Papers on the List： 0 Unfold All

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30 Days PV： 4

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