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author:

Zheng, Y.-R. (Zheng, Y.-R..) [1] | Liu, Y.-F. (Liu, Y.-F..) [2] | Liu, M.-H. (Liu, M.-H..) [3]

Indexed by:

Scopus PKU

Abstract:

Quaternary ammonium polyamine flocculants, denoted as PEDU, were prepared by polycondensation of urea, dimethylamine, ammonia and epichlorohydrin. The infrared spectrum analysis confirmed that PEDU contained quaternary ammonium group and hydroxyl group. The influences of molar ratios of urea and epichlorohydrin, dimethylamine and epichlorohydrin, ammonia and epichlorohydrin, reaction temperature and reaction time on the cationic degree of the polyamine flocculants and the CODCr removal percentage of papermaking wastewater were optimized by the orthogonal and single-factor experiments. The optimum conditions included 0.08:1.28:0.30:1 of the mole ration of urea, dimethylamine, ammonia and epichlorohydrin, 70° of the reaction temperature and 5 h of the reaction time. The cationic degree could reach 5.49 mmol/g when the PEDU was prepared at the optimum conditions. The results showed that the removal percentage of CODCr of papermaking wastewater could reach 67.9% when the flocculant dosage was 50 mg/L, pH value was 7.0 at room temperature.

Keyword:

Cationic degree; CODCr removal percentage; Papermaking wastewater; Quaternary ammonium polyamine flocculants

Community:

  • [ 1 ] [Zheng, Y.-R.]College of Environment and Resources, Fuzhou University, Fuzhou, Fujian Province, 350108, China
  • [ 2 ] [Zheng, Y.-R.]Fujian Provincial Technology Exploitation Base of Biomass Resources, Fuzhou, Fujian Province, 350108, China
  • [ 3 ] [Liu, Y.-F.]College of Environment and Resources, Fuzhou University, Fuzhou, Fujian Province, 350108, China
  • [ 4 ] [Liu, Y.-F.]Fujian Provincial Technology Exploitation Base of Biomass Resources, Fuzhou, Fujian Province, 350108, China
  • [ 5 ] [Liu, M.-H.]College of Environment and Resources, Fuzhou University, Fuzhou, Fujian Province, 350108, China
  • [ 6 ] [Liu, M.-H.]Fujian Provincial Technology Exploitation Base of Biomass Resources, Fuzhou, Fujian Province, 350108, China

Reprint 's Address:

  • 刘明华

    [Liu, M.-H.]College of Environment and Resources, Fuzhou University, Fuzhou, Fujian Province, 350108, China

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Source :

China Pulp and Paper

ISSN: 0254-508X

CN: 11-1967/TS

Year: 2011

Issue: 8

Volume: 30

Page: 34-38

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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