Hydrothermal synthesis and crystal structure of a novel polymolybdate with two kinds of organonitrogen ligands - Details

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Abstract：

A　novel　inorganic-organic　compound　(C4N2H　12)(C2N2H10)2[Mo　5P2O23]　(1)　has　been　synthesized　by　the　reaction　of　(NH4)2MoO4,　H3PO　4,　C2N2H8　(ethylenediaminium),　C4N2H10·6H2O　(piperazine　hexahydrate)　and　water　in　aqueous　solution　under　mild　hydrothermal　conditions.　Single-crystal　X-ray　analysis　reveals　that　the　title　compound　is　crystallized　in　the　triclinic　system,　space　group　P1　with　a　=　9.258(19),　b　=　9.382(19),　c　=　17.681(4)　Å,　α　=　76.28(3),　β　=　84.48(3),　γ　=　70.82(3)°,　V　=　1408.9(6)　Å3,　Mr　=　1122.04,　Z　=　2,　Dc　=　2.645　g/cm3,　μ　=　2.384　mm-1,　F(000)　=　1092.0,　the　final　R　=　0.0391,　wR　=　0.1185　and　S　=　1.006　for　6169　observed　reflections　with　I　>　2σ(I).　The　crystal　packing　is　stabilized　by　intra-　and　intermolecular　N-H···O　hydrogen　bonds　to　form　an　infinite　3D　network.

Keyword：

Crystal structure; Hybrid compounds; Hydrothermal synthesis; Polyoxometalate

Community：

[ 1 ] [Chen, W.-H.]College of Chemistry and Material Science, Longyan University, Longyan, Fujian 364000, China
[ 2 ] [Hu, Z.-B.]College of Chemistry and Material Science, Longyan University, Longyan, Fujian 364000, China
[ 3 ] [Zhang, Z.-S.]College of Chemistry and Material Science, Longyan University, Longyan, Fujian 364000, China
[ 4 ] [Qiu, Z.-H.]College of Chemistry and Material Science, Longyan University, Longyan, Fujian 364000, China
[ 5 ] [Qiu, Z.-H.]Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China
[ 6 ] [Zhou, Y.-L.]College of Chemistry and Material Science, Longyan University, Longyan, Fujian 364000, China
[ 7 ] [Zhao, J.-H.]College of Chemistry and Material Science, Longyan University, Longyan, Fujian 364000, China
[ 8 ] [Yuan, Q.-L.]College of Chemistry and Material Science, Longyan University, Longyan, Fujian 364000, China
[ 9 ] [Xiang, X.-Y.]College of Chemistry and Material Science, Longyan University, Longyan, Fujian 364000, China
[ 10 ] [Wang, X.-M.]College of Chemistry and Material Science, Longyan University, Longyan, Fujian 364000, China

Reprint 's Address：

[Hu, Z.-B.]College of Chemistry and Material Science, Longyan University, Longyan, Fujian 364000, China

Email：

huzhibiao@lyun.edu.cn

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Source ：

Jiegou Huaxue

ISSN： 0254-5861

CN： 35-1112/TQ

Year： 2011

Issue： 8

Volume： 30

Page： 1178-1182

0 . 4 4

JCR@2011

5 . 9 0 0

JCR@2023

ESI Discipline： CHEMISTRY;

JCR Journal Grade：4

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ESI Highly Cited Papers on the List： 0 Unfold All

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