A　novel　poly　(1-hexadecene-co-trimethylolpropane　trimethacrylate)　coating　was　prepared　and　applied　as　solidphasemicroextraction　(SPME)　for　analysis　of　pesticides　in　tea　samples.　This　SPME　coating　was　fabricated　on　the　surface　of　fiber　by　in-situ　copolymerization　of　1-hexadecene　and　trimethylolpropane　trimethacrylate,　in　the　presence　of　the　ternary　porogen　(cyclohexanol/1,　4-butanediol/water).　Both　the　effects　of　porogen　ratio　and　porogen　composition　on　the　SPME　performance　during　the　polymerization　process　were　investigated.　The　application　of　the　as-prepared　coating　was　evaluated　by　extracting　residual　pesticides　in　tea　samples.　Some　parameters　affecting　SPME　efficiency　such　as　extraction　time,　temperature,　pH,　ionic　strength　and　desorption　conditions　were　examined.　Good　linearity　of　the　calibration　curve　was　obtained　in　the　range　of　1.7-500　ng　ml-1　with　correlation　coefficient　(r)　better　than　0.9957.　The　detection　limits　(S/N　=　3)　for　six　pesticides　were　0.5-5.0　ng　ml-1　and　the　relative　standard　deviations　(RSDs)　of　precision　for　one　fiber,　fiber-tofiber,　and　day-to-day　were　7.0-10.8　%,　4.9-13.3　%　and　5.5-12.6　%,　respectively　(n　=　5).　Recoveries　obtained　at　spiked　tea　samples　were　80.8-108.8　%　for　different　analytes.　The　results　validated　the　as-prepared　coating　had　high　extraction　efficiency　toward　pesticides　as　well　as　good　solvent　resistant.　©　2011　Bentham　Science　Publishers.