Fe-Ti　pillared　bentonite　(Fe-Ti-B)　was　successfully　prepared　through　a　simple　cation　exchange　reaction.　The　obtained　sample　was　characterized　by　N2　adsorption-desorption,　X-ray　powder　diffraction,　and　inductively　coupled　plasma-atomic　emission　spectrometry.　The　effects　of　initial　pH,　catalyst　amount,　and　H2O2　concentration　on　photocatalysis-Fenton　degradation　of　phenol　were　investigated　in　detail.　The　results　showed　that　the　conversion　and　mineralization　rates　of　phenol　were　over　95%　at　pH　=　6.6　under　UV　light　irradiation.　At　the　same　time,　the　iron　leaching　rate　was　kept　below　2　mg/L　during　the　degradation　process.　The　performance　of　the　Fe-Ti-B　catalyst　is　superior　to　Fe-pillared　bentonite.　Moreover,　it　still　kept　a　high　activity　after　5　times　run,　indicating　that　Fe-Ti-B　is　a　highly　stable　catalyst.　The　degradation　rate　of　phenol　could　even　reach　70.3%　after　180　min　under　alkaline　conditions　(pH　=　9.0).　The　excellent　performance　of　Fe-Ti-B　may　be　attributed　to　its　large　surface　area　and　strong　surface　acidity.