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author:

Zhang, T. (Zhang, T..) [1] | Zhang, H. (Zhang, H..) [2] | Li, G. (Li, G..) [3] | Yung, H. (Yung, H..) [4]

Indexed by:

Scopus

Abstract:

High temperature interactions between glass-ceramic sealants and ferritic interconnects used in solid oxide fuel cells (SOFCs) lead to the formation of detrimental chromate phases, such as BaCrO4 or SrCrO4, which lead to the mechanical failure of the cell. In present work, the interactions are characterized using model reactions between Cr2O3 and glass powders. It is found that the addition of MnO2 reduces the formation of SrCrO4 more significantly than that of ZnO and La2O3, in the SOFCs operational temperature range (e.g., 900 °C). In addition, the mechanism of the reduction of the chromate phase by different additives is discussed in terms of the possible competing reactions. © 2010 Elsevier B.V. All rights reserved.

Keyword:

Chromate formation; Interfacial reaction; Model reaction; Sealing glass; Solid oxide fuel cells

Community:

  • [ 1 ] [Zhang, T.]Institute for Materials Research, Fuzhou University, Xueyuan Road 2#, Fuzhou, Fujian 350108, China
  • [ 2 ] [Zhang, H.]Institute for Materials Research, Fuzhou University, Xueyuan Road 2#, Fuzhou, Fujian 350108, China
  • [ 3 ] [Li, G.]Institute for Materials Research, Fuzhou University, Xueyuan Road 2#, Fuzhou, Fujian 350108, China
  • [ 4 ] [Yung, H.]Department of Materials Science and Engineering, National United University, Lienda 1#, Miao-Li, 36003, Taiwan

Reprint 's Address:

  • [Zhang, T.]Institute for Materials Research, Fuzhou University, Xueyuan Road 2#, Fuzhou, Fujian 350108, China

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Source :

Journal of Power Sources

ISSN: 0378-7753

Year: 2010

Issue: 19

Volume: 195

Page: 6795-6797

4 . 2 9

JCR@2010

8 . 1 0 0

JCR@2023

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 18

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 4

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